基于层流的微流体燃料电池的气透气式燃料电池.
Ranga S Jayashree1, Lajos Gancs, Eric R Choban
1Department of Chemical & Biomolecular Engineering, University of Illinois at Urbana-Champaign, 61801, USA.
Journal of the American Chemical Society
|December 1, 2005
概括
这项研究引入了一种带有新型气体扩散电极的透气微流体燃料电池 (LFFC). 这种设计通过改善氧气运输来显著提高功率密度,克服了以前的限制.
科学领域:
- 电化学 电化学 电化学
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
背景情况:
- 之前的基于层状流量的微流体燃料电池 (LFFC) 由于氧溶性差和在水中运输缓慢而受到阴极限制.
- 这些质量转移问题阻碍了燃料电池的整体性能和功率密度.
研究的目的:
- 设计和描述一个改进的透气层流式微流体燃料电池 (LFFC).
- 解决和克服之前LFFC设计中观察到的阴极限性性能问题.
主要方法:
- 将呼吸气体扩散电极作为阴极的结合.
- 使用酸燃料和空气阴极对LFFC性能进行表征.
- 功率密度与以前使用水性氧源的LFFC设计进行比较.
主要成果:
- 呼吸空气的LFFC设计显著提高了氧气补充在阴极由于更高的氧气扩散在空气中.
- 实现了26mW/cm2的功率密度,与以前的设计相比增加了五倍 (约. 5mW/cm2) 的情况.
- 减轻了阴极质量转移限制,使燃料电池的进一步优化成为可能.
结论:
- 空气呼吸气体扩散电极有效地解决了LFFC中的氧气运输限制.
- 这一进步释放了提高燃料利用率和电极性能的潜力.
- 呼吸空气的LFFC为未来的微流体能源应用提供了有希望的优势.
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