直接的实验证据表明,伴随着玻璃过渡的日益长的尺度伴随着玻璃过渡
L Berthier1, G Biroli, J-P Bouchaud
1Laboratoire des Colloïdes, Verres, et Nanomatériaux, UMR 5587, Université Montpellier II and CNRS, 34095 Montpellier, France. berthier@lcvn.univ-montp2.fr
概括
研究人员探索了玻璃形成,引入了测量动态关联长度的新方法. 这提供了实验证据,证明随着粘度在玻璃化过渡过程中增加,更大的材料区域必须一起移动.
科学领域:
- 材料科学 材料科学 材料科学
- 化学物理 化学物理
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 液体在没有结晶的情况下变得高度粘性的玻璃过渡的性质仍然是材料科学中的一个基本挑战.
- 一个长期的假设表明,较大的分子或体区域的合作运动是玻璃过渡附近越来越高的粘度的基础.
研究的目的:
- 实验性地研究动态异质性在玻璃形成中的作用.
- 在玻璃过渡期间量化测量合作重组地区的大小.
主要方法:
- 开发和应用新的多点动态灵敏度.
- 对分子液体和合物悬浮物的实验分析.
主要成果:
- 证明了玻璃形成和增加动态相关长度之间的直接实验联系.
- 定量估计了超冷液体中动态相关区域的大小.
结论:
- 这项研究提供了令人信服的实验证据,支持在玻璃过渡过程中不断增长的动态相关长度理论.
- 引入的方法为表征玻璃系统的动态提供了一个新的工具.
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