在水溶液中分层的双氧化物纳米颗粒的稳定悬浮
Zhi Ping Xu1, Gregory S Stevenson, Chao-Qing Lu
1ARC Centre for Functional Nanomaterials, School of Engineering, Queensland Brain Institute, University of Queensland, Brisbane QLD 4072, Australia.
Journal of the American Chemical Society
|January 5, 2006
概括
热水处理有效地分散聚合的多层双氧化物 (LDH) 聚合物. 这一过程产生了稳定的悬浮液,其中含有尺寸在50-300nm之间的均LDH颗粒.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 化学 化学 化学
背景情况:
- 聚合层双氧化物 (LDH) 结构在各种应用中构成挑战.
- 获得稳定,分散良好的LDH颗粒对于材料加工和性能至关重要.
研究的目的:
- 为了研究水热处理在分散聚合LDH的有效性.
- 为了描述LDH颗粒在处理后的尺寸和稳定性.
主要方法:
- 在特定条件下将聚合LDH进行热水处理.
- 通过颗粒大小分析和稳定性测试分析得到的悬浮物.
主要成果:
- 水热处理成功地分解了LDH聚合物.
- 获得了均且稳定的悬浮剂.
- 分散的LDH粒子大小在50至300纳米之间.
结论:
- 热水处理是从聚合材料中生产稳定的纳米级LDH悬浮物的可行方法.
- 实现的可控颗粒大小对先进材料应用有影响.
相关概念视频
Colloids
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
Colloids and Suspensions
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
Colloidal precipitates
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
Coagulation
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
The Electrical Double Layer
In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
The Colloidal State
The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called the...


