在气相S(N) 2和E2反应中的动态同位素效应:实验与理论的比较

Stephanie M Villano1, Shuji Kato, Veronica M Bierbaum

  • 1University of Colorado, Department of Chemistry and Biochemistry, 215 UCB, Boulder, Colorado 80309-0215, USA.

概括

这项研究研究了化与化离子的气相反应,揭示了随着基组替代增加,消除反应成为主导的. 乙基化物的实验结果偏离了计算预测.

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