水滴在平面聚合物表面的滑动行为
Naoya Yoshida1, Yuu Abe, Hiroaki Shigeta
1Research Center for Advanced Science and Technology, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904, Japan. naoya@wlab.rcsat.u-tokyo.ac.jp
Journal of the American Chemical Society
|January 19, 2006
概括
化聚合物薄膜根据的度显示可调节的疏水性. 这影响了水滴的行为,从稳定运动过渡到加速,因为表面变得更加疏水.
科学领域:
- 聚合物科学 聚合物科学
- 表面化学 表面化学
- 材料科学 材料科学 材料科学
背景情况:
- 疏水性是各种材料应用的关键性质.
- 控制聚合物的表面特性是定制材料性能的关键.
- 化聚合物以其独特的表面特性而闻名.
研究的目的:
- 调查甲基甲酸-甲基甲酸共聚物中含量和疏水性之间的关系.
- 了解不同含量如何影响这些聚合物薄膜的静态和动态湿行为.
- 探索静态疏水性对水滴滑动行为的影响.
主要方法:
- 制备甲基甲烯酸和甲基甲烯酸的平面共聚合物薄膜.
- 在共聚合物结构内化度的系统变化.
- 测量静态水接触角度以量化表面的疏水性.
- 观察和分析水滴在准备好的表面上的滑动行为.
主要成果:
- 在度和聚合物表面的静态疏水性之间发现了直接的,系统的相关性.
- 发现水滴的滑动行为取决于静态水性.
- 水接触角度的增加导致滑动运动从恒定速度转变为恒定加速度.
结论:
- 的度是这些共聚合物中静态水性的关键决定因素.
- 表面的疏水性显著影响了聚合物薄膜上的水滴的动态行为.
- 这些发现为设计具有可控湿化和滑动特性的表面提供了先进应用的见解.
相关概念视频
States of Water
Water exists in any one of the three classical states: solid (ice), liquid (water), and gas (steam or water vapor). The state of water depends on i) the intermolecular forces that draw molecules together and ii) the kinetic energy that leads to movements that pull them apart.
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
Adhesion
Adhesion occurs when one type of molecule is attracted to a different molecule. Water exhibits adhesive properties in the presence of polar surfaces, such as glass or cellulose in plants. For instance, when water is poured into a glass, the positively charged hydrogen molecules of water are more attracted to the negatively charged oxygen molecules in the silica than to the oxygen in neighboring water molecules.
Capillary action is a result of water’s adhesive tendencies. When a narrow glass...
Capillary action is a result of water’s adhesive tendencies. When a narrow glass...
Cohesion
Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a surface,...
On a surface,...
Surface Tension, Capillary Action, and Viscosity
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
Surface Tension
Surface tension is defined as the force per unit length (γ) acting along the surface of a liquid. It arises due to strong intermolecular forces of attraction. A molecule located inside the bulk of the liquid is surrounded by other molecules and experiences equal forces in all directions. However, a molecule at the surface experiences unbalanced forces because there are more neighboring molecules below than above. This creates a net inward force that pulls surface molecules toward the interior,...
Surface Tension of Fluid
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies with...
Surface tension varies with...


