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Updated: Jul 19, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
10:10

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

Published on: July 28, 2018

异质催化中的化学区域选择性:从理论方法来看,对C = O和C = C化有竞争性路径

David Loffreda1, Françoise Delbecq, Fabienne Vigné

  • 1Laboratoire de Chimie, UMR CNRS 5182, Ecole Normale Supérieure de Lyon, France. David.Loffreda@ens-lyon.fr

Journal of the American Chemical Society
|January 26, 2006
PubMed
概括

这项研究挑战了催化化的典型反应性规则. 密度函数理论的计算表明,碳基组 (C=O) 在表面的烯酸中优先化,而不是碳-碳双键 (C=C).

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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)08:25

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Published on: January 17, 2020

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