低价值介导的C-F/C-H键的双激活:从o-arylatedalpha,alpha,alpha-trifluorotoluene衍生物中合成烯.

Kohei Fuchibe¹, Takahiko Akiyama

¹Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan.

Journal of the American Chemical Society

|February 2, 2006

概括

五化物 (NbCl5) 和化 (LiAlH4) 处理的三二甲产生衍生物. 这种反应激活了三甲基组中的C-F键和相邻的C-H键,以实现高效的合.

相关概念视频

您也可能阅读

通过共同作者、期刊和引用图与本文相关的文章。

排序

Same author

Visible-Light-Driven Enantioselective Free Radical Addition to Aldimines via Direct C-H Functionalization.

Organic letters·2026

Same author

Regiodivergent Synthesis of <i>gem</i>-Difluoroalkenes Enabled by Electron Donor-Acceptor Complex-Mediated C-F Bond Photoreduction of α-Trifluoromethylstyrenes.

Organic letters·2026

Same author

Direct-Excitation-Enabled Radical Hydrosilylation via a Silyl Radical Precursor.

Organic letters·2026

相关实验视频

低价值介导的C-F/C-H键的双激活:从o-arylatedalpha,alpha,alpha-trifluorotoluene衍生物中合成烯.

相关概念视频

Visible-Light-Driven Enantioselective Free Radical Addition to Aldimines via Direct C-H Functionalization.

Regiodivergent Synthesis of <i>gem</i>-Difluoroalkenes Enabled by Electron Donor-Acceptor Complex-Mediated C-F Bond Photoreduction of α-Trifluoromethylstyrenes.

Direct-Excitation-Enabled Radical Hydrosilylation via a Silyl Radical Precursor.

Visible-Light-Driven Photocatalytic Utilization of Sulfur Hexafluoride (SF<sub>6</sub>) as an SF<sub>5</sub> Radical Source.

Perioperative and oncological outcomes of extended surgery for colorectal cancer in younger patients: a propensity score-matched study.

Transfer Hydrogenation of β‑Trifluoromethylated Nitroalkenes Catalyzed by Chiral Calcium Phosphate.

相关实验视频

低价值介导的C-F/C-H键的双激活:从o-arylatedalpha,alpha,alpha-trifluorotoluene衍生物中合成烯.

相关概念视频

Visible-Light-Driven Enantioselective Free Radical Addition to Aldimines via Direct C-H Functionalization.

Regiodivergent Synthesis of <i>gem</i>-Difluoroalkenes Enabled by Electron Donor-Acceptor Complex-Mediated C-F Bond Photoreduction of α-Trifluoromethylstyrenes.

Direct-Excitation-Enabled Radical Hydrosilylation via a Silyl Radical Precursor.

Visible-Light-Driven Photocatalytic Utilization of Sulfur Hexafluoride (SF<sub>6</sub>) as an SF<sub>5</sub> Radical Source.

Perioperative and oncological outcomes of extended surgery for colorectal cancer in younger patients: a propensity score-matched study.

Transfer Hydrogenation of β‑Trifluoromethylated Nitroalkenes Catalyzed by Chiral Calcium Phosphate.

相关实验视频

低价值介导的C-F/C-H键的双激活:从o-arylatedalpha,alpha,alpha-trifluorotoluene衍生物中合成烯.

相关概念视频

相关文章

Visible-Light-Driven Enantioselective Free Radical Addition to Aldimines via Direct C-H Functionalization.

Regiodivergent Synthesis of <i>gem</i>-Difluoroalkenes Enabled by Electron Donor-Acceptor Complex-Mediated C-F Bond Photoreduction of α-Trifluoromethylstyrenes.

Direct-Excitation-Enabled Radical Hydrosilylation via a Silyl Radical Precursor.

Visible-Light-Driven Photocatalytic Utilization of Sulfur Hexafluoride (SF<sub>6</sub>) as an SF<sub>5</sub> Radical Source.

Perioperative and oncological outcomes of extended surgery for colorectal cancer in younger patients: a propensity score-matched study.

Transfer Hydrogenation of β‑Trifluoromethylated Nitroalkenes Catalyzed by Chiral Calcium Phosphate.

相关实验视频

低价值介导的C-F/C-H键的双激活:从o-arylatedalpha,alpha,alpha-trifluorotoluene衍生物中合成烯.

相关概念视频

相关文章

Visible-Light-Driven Enantioselective Free Radical Addition to Aldimines via Direct C-H Functionalization.

Regiodivergent Synthesis of <i>gem</i>-Difluoroalkenes Enabled by Electron Donor-Acceptor Complex-Mediated C-F Bond Photoreduction of α-Trifluoromethylstyrenes.

Direct-Excitation-Enabled Radical Hydrosilylation via a Silyl Radical Precursor.

Visible-Light-Driven Photocatalytic Utilization of Sulfur Hexafluoride (SF<sub>6</sub>) as an SF<sub>5</sub> Radical Source.

Perioperative and oncological outcomes of extended surgery for colorectal cancer in younger patients: a propensity score-matched study.

Transfer Hydrogenation of β‑Trifluoromethylated Nitroalkenes Catalyzed by Chiral Calcium Phosphate.

科学领域:

背景情况:

研究的目的:

主要方法:

主要成果:

结论: