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Updated: Jul 18, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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催化"点击"罗塔克桑:一个subsoichiometric金属模板通道到机械互锁的架构

Vincent Aucagne1, Kevin D Hänni, David A Leigh

  • 1School of Chemistry, University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh EH9 3JJ, United Kingdom.

Journal of the American Chemical Society
|February 16, 2006
PubMed
概括

本研究介绍了一种简单的方法,用于创建机械互锁的分子,使用一种催化剂量铜 (I) 和随时可用的试剂. 这一突破简化了复杂的轮素结构的合成,使它们更容易获得.

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Heterogeneous Catalysis01:22

Heterogeneous Catalysis

Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...