分子O2与二重和三重化[UO2]+的结合
Gary S Groenewold1, Kevin C Cossel, Garold L Gresham
1Department of Chemical Sciences, Idaho National Laboratory, 2525 North Fremont Avenue, Idaho Falls, ID 83415-2208, USA. gary.groenewold@inl.gov
Journal of the American Chemical Society
|March 2, 2006
概括
氧 ((V) 复合物与乙或水结合时与二氧化物结合. 这种结合取决于连接物的数量和的含量.
科学领域:
- 无机化学 无机化学 有机化学
- 有机金属化学 有机金属化学
- 化学 的化学
背景情况:
- 离子与二氧化物的反应性对于理解氧化还原过程至关重要.
- 二氧化 ((V) ([UO(2)] ((+)) 是一个独特的氧化状态,具有不配对的电子,影响其协调化学.
研究的目的:
- 为了研究二氧化 (V) 复合物与二氧化的气相反应.
- 确定影响二氧化碳与[UO(2) ](+) 离子结合的因素.
主要方法:
- 气相离子-分子反应.
- 碰撞诱导解离 (CID) 的研究.
主要成果:
- 与两个或三个乙或水分子结合的二氧化 (V) 酸盐与二氧化反应.
- 发现二氧化物结合强度在第二和第三个联结体之间是中间的.
- 对于零,一个或四个配体的[UO(2) ](+) 或类似的U(IV) 或U(VI) 种类,没有发生二氧化物结合.
结论:
- 对[UO(2)](+) 的二氧化物结合是依赖于连接体的,需要特定的协调号码.
- 观察到的二氧化碳结合机制与典型的电子受体行为不同,这表明与U(V) 中心的独特相互作用.
- 在乌拉尼尔价值轨道中存在未配对的电子和供体连接体,便于这种替代的二氧化物结合方式.
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