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Updated: Aug 10, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

3,3'-Bis(trisarylsilyl) 替代的双甲酸稀土金属催化剂用于不对称的胺化

Denis V Gribkov1, Kai C Hultzsch, Frank Hampel

  • 1Institut für Organische Chemie, Friedrich-Alexander Universität Erlangen-Nürnberg, Henkestrasse 42, D-91054 Erlangen, Germany.

Journal of the American Chemical Society
|March 16, 2006
PubMed
概括

新的奇拉稀土金属复合物有效催化氨基基的不对称胺化/循环化反应,实现高产率和高达95%的异能选择性. 这些催化剂还使性氨基的动态分辨率能够具有出色的二选择性.

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