小直径单壁碳纳米管的垂直阵列生长
Ya-Qiong Xu1, Erica Flor, Myung Jong Kim
1Department of Electrical & Computer Engineering, Rice University, MS-100, 6100 Main Street, Houston, Texas 77005, USA.
Journal of the American Chemical Society
|May 18, 2006
概括
一种新的热丝化学蒸气沉积技术成功地生长了单壁碳纳米管 (SWNT) 的垂直阵列. 这种方法利用高温激活含碳气体,使得SWNT在先进材料应用中能够得到控制的生长.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 化学工程是化学工程的重要组成部分.
背景情况:
- 单壁碳纳米管 (SWNT) 的垂直阵列为各种应用提供了独特的特性.
- 具有特定直径和方向的SWNTs的受控合成仍然是一个挑战.
研究的目的:
- 开发和演示用于生长垂直阵列SWNTs的热丝化学蒸气沉积 (HFCVD) 方法.
- 描述合成的SWNTs的结构和形态特性.
主要方法:
- 使用热导线 (T>2000°C) 在低大气压下激活含和碳的气体混合物.
- 用铁装饰的基板放置在预热炉中,用于SWNT生长.
- 使用拉曼光谱,光谱,扫描电子显微镜 (SEM) 和传输电子显微镜 (TEM) 进行了SWNT阵列的特征.
主要成果:
- 成功合成了SWNT的垂直阵列,直径控制在0.78至1.6纳米之间.
- 证明了HFCVD方法在产生垂直对齐的SWNT结构中的有效性.
- 鉴定证实了SWNT阵列的形成和质量.
结论:
- 开发的HFCVD方法对于生产垂直阵列单壁碳纳米管是有效的.
- 这种技术为高级应用提供了可扩展合成垂直对齐SWNT的途径.
- 进一步的研究可以探索为量身定制的SWNT属性优化生长参数.
相关概念视频
Chromatin Packaging
Each human somatic cell contains 6 billion base-pairs of DNA. Each base-pair is 0.34 nm long, which means that each diploid cell contains a staggering 2 meters of DNA. How is such a long DNA strand packed inside a nucleus measuring only 10 - 20 microns in diameter?
The chromatin
In combination with specialized DNA binding protein called Histones, the DNA double helix forms a compact DNA: protein complex called chromatin. The chromatin itself is further compacted into higher-order structures.
The chromatin
In combination with specialized DNA binding protein called Histones, the DNA double helix forms a compact DNA: protein complex called chromatin. The chromatin itself is further compacted into higher-order structures.
Generation of Straight or Branched Actin Filaments
The straight or branched structure formation of actin filaments is controlled by nucleating proteins such as the formins and Arp2/3 complex. Formin-mediated assembly results in straight filaments, whereas Arp2/3 protein complex-mediated assembly results in branched actin filaments.
Arp2/3 Complex
Arp2/3 complex is a seven-subunit complex consisting of two proteins similar to actin- Arp2 and Arp3, and five other subunits that help keep Arp2 and Arp3 inactive. When required, the complex is...
Arp2/3 Complex
Arp2/3 complex is a seven-subunit complex consisting of two proteins similar to actin- Arp2 and Arp3, and five other subunits that help keep Arp2 and Arp3 inactive. When required, the complex is...
Formation of Intermediate Filaments
Intermediate filaments are cytoskeletal proteins with higher tensile strength and flexibility than microfilaments and microtubules. Unlike the other two cytoskeletal proteins, intermediate filament formation lacks the enzymatic activity to hydrolyze nucleotides like ATP and GTP to generate energy for polymerization. Therefore, the formation of intermediate filaments is multistep self-assembly. The involvement of any accessory proteins in intermediate filament formation has not yet been reported.
Radical Chain-Growth Polymerization: Mechanism
The radical chain-growth polymerization mechanism consists of three steps: initiation, propagation, and termination of polymerization. The polymerization initiates when a free radical generated from the radical initiator adds to the unsaturated bond in the monomer. The unpaired electron of the free radical and one π electron in the unsaturated bond creates a σ bond between the free radical and the monomer. As a result, the other π electron in the unsaturated bond converts this species into the...
Radical Chain-Growth Polymerization: Chain Branching
The skeletal structure of polymers synthesized via radical polymerization is always branched. For example, the polymerization of ethylene by radical polymerization results in a low-density grade of polyethylene with a heavily branched skeletal structure. Here, the radical site abstracts hydrogen from the growing chain, and the radical site shifts from the end (a primary carbon center) to anywhere within the growing chain (a secondary carbon center). Consequently, the part of the chain from the...
Chromatin Packaging
Each human somatic cell contains 6 billion base pairs of DNA. Each base pair is 0.34 nm long, meaning each diploid cell contains a staggering 2 meters of DNA. This long DNA strand is packed inside a nucleus measuring only 10-20 microns in diameter with the help of specialized DNA-binding proteins called histones. Together they form a compact DNA-protein complex called chromatin. The chromatin is further compacted into higher-order structures. The highest level of compaction is achieved during...


