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Updated: Jul 18, 2026

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
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Published on: January 30, 2015

功能化芳香三乙烯乙烯的热循环二氧化合成和电子因素

Bryan K Spraul1, S Suresh, Jianyong Jin

  • 1Department of Chemistry and Center for Optical Materials Science and Engineering Technologies (COMSET), Clemson University, Clemson, South Carolina, USA.

Journal of the American Chemical Society
|May 25, 2006
PubMed
概括

新的芳香三乙烯乙烯被合成并循环二化,形成高环 (PFCB) 化合物. 电子吸收组被发现可以降低这种重要的聚合反应的速率.

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The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
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