混合生产和储存,随后进行碳结晶
Angela D Lueking1, Humberto R Gutierrez, Dania A Fonseca
1The Pennsylvania State University, 120 Hosler, University Park, Pennsylvania 16802-5000, USA. adl11@psu.edu
Journal of the American Chemical Society
|June 15, 2006
概括
这项研究揭示了低温的释放和捕获在改性炭煤中. 加热加速了这种的进化,这表明它推动了新的晶体碳结构的形成.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
- 地质化学 地质化学
背景情况:
- 炭化煤衍生物可以通过反应性球磨来合成.
- 高能耗的削工艺可以创建超稳定的碳结构.
研究的目的:
- 为了研究低温气演变和捕获在炭酸煤衍生物中.
- 探索释放和碳结构转换之间的关系.
主要方法:
- 用循环烯对炭石煤进行反应性球磨.
- 拉曼光谱检测分子振动.
- 热分析以研究的演变动力学.
- 显微镜和光谱学用于表征碳结构.
主要成果:
- 低温气演变的证据和在炭酸煤衍生物中被困的证据.
- 在室温下观察到的释放,通过加热至60°C以上而加速.
- 晶体碳的形成,包括纳米晶体钻石和石墨区域.
- 一种被无形碳包围的新型晶体碳形式的鉴定.
结论:
- 的捕获和缓慢释放发生在磨炭炭酸煤衍生物中.
- 的进化似乎诱导无形碳材料的结晶.
- 变态稳定的化碳重新排列成更稳定的形式,释放分子.
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