长距离的结构顺序,莫埃尔图案,以及乳稳定泡中的虹彩
Syuji Fujii1, Anthony J Ryan, Steven P Armes
1Department of Chemistry, Dainton Building, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, United Kingdom. s.fujii@chem.oit.ac.jp
Journal of the American Chemical Society
|June 15, 2006
概括
可以轻松生产稳定,稳固的聚乙烯泡. 这些泡在干燥后保持完整,与传统剂稳定的泡不同,在安全油墨中具有潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 合体和表面化学
背景情况:
- 传统的泡往往缺乏长期稳定性,特别是在干燥后.
- 稳定剂,如二二甲基硫酸盐或聚乙烯 (N-维尼尔pyrrolidone) 可能是不足以坚固的泡结构.
研究的目的:
- 研究易于生产高稳定性泡的方法.
- 为了探索仅由微米大小的,稳固的聚乙烯 (PS) 乳颗粒稳定的泡.
- 评估这些PS稳定泡的稳定性和性能.
主要方法:
- 使用固体稳定聚烯乳颗粒生产泡.
- 在湿和干状态下进行稳定性测试.
- 显微镜技术包括扫描电子显微镜 (SEM) 和光学显微镜.
主要成果:
- 由PS乳颗粒稳定的泡表现出异常的稳定性,在湿后存活超过一年,在干燥后保持完整.
- 干燥揭示了六角密集的PS粒子阵列,表明高合物稳定性.
- 光学显微镜显示了具有远程顺序的精确定义的乳双层,形成局部化moiré模式.
- 干燥的泡呈现出高色,这表明了潜在的应用.
结论:
- 立体稳定聚烯乳颗粒为泡提供了比传统剂更好的稳定性.
- 干燥的PS稳定泡的有序结构有助于它们独特的光学特性.
- 这些稳定,虹彩的泡对安全油墨和涂料的应用具有前景.
更多相关视频
相关概念视频
Molecular Shapes
Molecules have characteristic shapes that are crucial for their function. The arrangement of various electron groups around the central atom dictates their molecular geometry. Electron pairs in the valence shell of a central atom will adopt an arrangement that minimizes repulsions between the electron pairs by maximizing the distance between them. The valence electrons form either bonding pairs, located primarily between bonded atoms, or lone pairs.Two regions of electron density in a diatomic...
Membrane Fluidity
Membrane fluidity is explained by the fluid mosaic model of the cell membrane, which describes the plasma membrane structure as a mosaic of components—including phospholipids, cholesterol, proteins, and carbohydrates—that gives the membrane a fluid character.
Mosaic nature of the membrane
The mosaic characteristic of the membrane helps the plasma membrane remain fluid. The integral proteins and lipids exist as separate but loosely-attached molecules in the membrane. The membrane is a relatively...
Mosaic nature of the membrane
The mosaic characteristic of the membrane helps the plasma membrane remain fluid. The integral proteins and lipids exist as separate but loosely-attached molecules in the membrane. The membrane is a relatively...
Newman Projections
Different notations are used to represent the three-dimensional structure of molecules on two-dimensional surfaces. One of the most commonly used representations is the dash-wedge formula. The dashed wedges, solid wedges, and the plane lines indicate the groups situated behind the plane, coming out of the plane, and in the plane, respectively.
The organic molecules rotate across the single bonds leading to numerous temporary three-dimensional structures of varying energy known as conformers.
The organic molecules rotate across the single bonds leading to numerous temporary three-dimensional structures of varying energy known as conformers.
Structure of Amines
The hybridized nitrogen atom in amines possesses a lone pair of electrons and is bound to three substituents with a bond angle of around 108°, which is less than the tetrahedral angle of 109.5°. However, the C–N–H bond angle is slightly larger at 112°, with a carbon–nitrogen bond length of 147 pm. This carbon–nitrogen bond length of of amines is longer than the carbon–oxygen bond of alcohols (143 pm) but shorter than alkanes’ carbon–carbon bond (154 pm). These aspects are illustrated in Figure...
Colloidal precipitates
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
Micelles
Micelle formation is an intricate process that hinges on the properties of amphiphilic or amphipathic molecules and the conditions of the system in which they are found. Amphiphilic molecules, which have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts, play a critical role in this process.In aqueous environments, these molecules arrange themselves such that their hydrophilic heads are turned towards the water phase, while their hydrophobic tails are oriented away...


