元素分区:融结构和组成的作用
M W Schmidt1, J A D Connolly, D Günther
1Institut für Mineralogie und Petrologie, Department of Earth Sciences, Eidgenössische Technische Hochschule (ETH), 8092 Zürich, Switzerland. max.schmidt@erdw.ethz.ch
概括
高压实验表明,融结构显著影响了在共存的加布洛和花岩融之间分离的微量元素. 这一发现对于理解岩演变和地球元素分布至关重要.
科学领域:
- 地质化学 地质化学
- 石化学 石化学是一门学科.
- 实验性石化学 实验性石化学
背景情况:
- 微量元素在晶体和融体之间的分离对于理解岩分化和火性岩石的形成至关重要.
- 融化结构受到成分,压力和温度的影响,越来越被认为是元素行为的一个关键因素.
研究的目的:
- 实验性地确定融结构对痕元素在共存的加布洛和花岩融之间分隔的影响.
- 量化融化结构对晶体/融化分区系数的贡献.
- 研究元素属性 (例如,场强度) 和它们的分区行为之间的关系.
主要方法:
- 通过高压,高温离心法分离并存的加布罗和花岩融物.
- 使用激光除感应合等离子质谱法 (LA-ICP-MS) 分析分离化的微量元素成分.
- 应用常规溶液模型来预测观察到的分区效应.
主要成果:
- 融化结构约占晶体/融化分区系数大小差异的一级.
- 和性土元素的分离强烈依赖于它们的电场强度.
- 特定的元素组 (安福特,单双电子,稀土,过渡,高电场强度) 呈现出不同的分离偏好,由聚合和协调控制.
结论:
- 融化结构是微量元素分离的主要控制因素,显著影响了岩演化模型.
- 观察到的分区趋势可以使用常规解决方案模型预测,突出强调热力学方法的重要性.
- 这项研究为复杂的岩系统中微量元素的行为提供了关键的见解.
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