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相关概念视频

Carbon Skeletons01:12

Carbon Skeletons

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Life on Earth is carbon-based, as all macromolecules that make up living organisms contain carbon atoms. All organic compounds have a carbon backbone. Each carbon atom is tetravalent and can bond with four other atoms, making it an extraordinarily flexible component of biological molecules. Because carbon’s valence electrons are stable, it rarely becomes an ion. As the carbon chain increases in length, structural modifications such as ring structures, double bonds, and branching side...
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The Carbon Cycle01:14

The Carbon Cycle

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Carbon is the basis of all organic matter on Earth, and is recycled through the ecosystem in two primary processes: one in which carbon is exchanged among living organisms, and one in which carbon is cycled over long periods of time through fossilized organic remains, weathering of rocks, and volcanic activity. Human activities, including increased agricultural practices and the burning of fossil fuels, has greatly affected the balance of the natural carbon cycle.
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Applications of the Ideal Gas Law: Molar Mass, Density, and Volume03:43

Applications of the Ideal Gas Law: Molar Mass, Density, and Volume

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The volume occupied by one mole of a substance is its molar volume. The ideal gas law, PV = nRT, suggests that the volume of a given quantity of gas and the number of moles in a given volume of gas vary with changes in pressure and temperature. At standard temperature and pressure, or STP (273.15 K and 1 atm), one mole of an ideal gas (regardless of its identity) has a volume of about 22.4 L — this is referred to as the standard molar volume.
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Phase Diagrams02:39

Phase Diagrams

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A phase diagram combines plots of pressure versus temperature for the liquid-gas, solid-liquid, and solid-gas phase-transition equilibria of a substance. These diagrams indicate the physical states that exist under specific conditions of pressure and temperature and also provide the pressure dependence of the phase-transition temperatures (melting points, sublimation points, boiling points). Regions or areas labeled solid, liquid, and gas represent single phases, while lines or curves represent...
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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Carbonation Shrinkage01:24

Carbonation Shrinkage

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Atmospheric CO2 penetrates the concrete's pores and, in the presence of moisture, forms carbonic acid, which then reacts with calcium hydroxide in the hydrated cement, forming calcium carbonate. This process reduces the concrete's volume and is termed carbonation shrinkage.
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction...
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相关实验视频

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Preparing Silica Aerogel Monoliths via a Rapid Supercritical Extraction Method
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无形的类似二氧化碳的二氧化碳.

Mario Santoro1, Federico A Gorelli, Roberto Bini

  • 1LENS, European Laboratory for Non-linear Spectroscopy and INFM, Via N. Carrara 1, I-50019 Sesto Fiorentino, Firenze, Italy. santoro@lens.unifi.it

Nature
|June 17, 2006
PubMed
概括

研究人员合成了一种新型无形形式的二氧化碳 (a-CO2),称为二氧化碳.

科学领域:

  • 材料科学 材料科学 材料科学
  • 化学 化学 化学
  • 物理 物理学 物理

背景情况:

  • 二氧化碳 (CO2) 通常与氧气形成双键.
  • 与二氧化 (SiO2) 和 (GeO2) 不同,无形二氧化碳在环境条件下没有合成.
  • 以前的无形二氧化碳形式只是理论上的,通过模拟来预测.

研究的目的:

  • 为了合成和描述一种新的无形,类似于二氧化碳 (a-CO2) 的二氧化碳 (a-CO2) 的形式.
  • 在高压和高温下研究二氧化碳的结构和结合变化.
  • 为了确定a-CO2是否与其他IV组二氧化碳玻璃结构相同.

主要方法:

  • 在室温下压缩分子二氧化碳 (第三阶段) 在40至48GPa之间.
  • 使用红外光谱学的分析,观察键形成和分子特征.
  • 使用拉曼光谱和同步射线X射线衍射来确定无形结构的特征.

主要成果:

  • 成功合成一种非分子形态的二氧化碳 ("a-carbonia").
  • 在压力下观察到从C=O双键转化为C-O单键.
  • 确认无形结构和结构同质性与无形二氧化和germania.

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结论:

  • 网络形成无序系统的类别现在包括无形二氧化碳 (a-CO2).
  • 这一发现扩大了我们对IV组二氧化物及其无形相的理解.
  • a-CO2代表了一种新材料,在材料科学中具有潜在的应用.