乙烯和甲基乙烯功能对Si(111) 表面的共价附着:用于有机表面功能化的支架,同时保留Si(111) 表面位点的Si-C被动化
Patrick T Hurley1, E Joseph Nemanick, Bruce S Brunschwig
1Division of Chemistry and Chemical Engineering, 127-72, California Institute of Technology, Pasadena, California 91125, USA.
Journal of the American Chemical Society
|August 3, 2006
概括
用Si-CC-R物种对表面进行功能化,可以创建稳定,碳终结材料. 这些表面抗氧化,可以进一步改造,保持理想的化学和电气性能.
科学领域:
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
- 纳米技术 纳米技术
背景情况:
- (Si) 表面在电子学中至关重要.
- 控制表面终端是设备性能的关键.
- 对于Si表面功能化的现有方法有局限性.
研究的目的:
- 开发一种可靠的方法来使111表面具有功能.
- 在Si(111) 上创建稳定的-碳键.
- 探索这些功能化表面的进一步改造.
主要方法:
- 两步反应:化H-Si(111) 随后与有机试剂 (Na-CC-H或CH3-CC-Na) 进行反应.
- 使用X射线光电子谱学 (XPS) 和红外 (IR) 谱学进行表征.
- 电化学测量以评估氧化阻力.
主要成果:
- 在Si-CC-R (R=H,CH3) 物种中成功实现了Si(111) 的功能化.
- 没有检测到功能化表面的氧化.
- 在红外光谱学中观察特征性的,极化CC延伸.
- 通过XPS确认Si-C结合.
- 在保持表面性质的同时,证明了与基的进一步功能化.
结论:
- 开发的方法提供了稳定的,碳终结的Si111) 表面.
- 这些表面表现出极好的抗氧化能力.
- 功能化的表面可以进一步修改为先进的应用程序,保留Si-C终端.
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