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Updated: Jul 25, 2026

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7-d-和8-d-双循环[4.2.0]oct-2-的热反应

John E Baldwin1, Phyllis A Leber, David C Powers

  • 1Department of Chemistry, Syracuse University, Syracuse, New York 13244, USA. jbaldwin@syr.edu

Journal of the American Chemical Society
|August 3, 2006
PubMed
概括

双环[4.2.0]oct-2-ene的热反应显示C1-C8键同解,形成一个稳定的二基中间体. 这条路径,而不是轨道对称性,决定了[1,3]碳转移的立体化学.

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