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相关概念视频

Functional Groups02:45

Functional Groups

Functional groups are a group of atoms with characteristic properties, which when linked to the carbon skeleton of a molecule, alter the properties of that molecule. For example, the presence of certain functional groups on a molecule will make them hydrophilic, whereas others will make them hydrophobic. These functional groups are an indispensable part of organic chemistry and important components of biological molecules, such as carbohydrates, proteins, lipids, and nucleic acids. Each...
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
2° Amines to N-Nitrosamines: Reaction with NaNO201:20

2° Amines to N-Nitrosamines: Reaction with NaNO2

Secondary amines react with nitrous acid to form N-nitrosamines, as depicted in Figure 1. Nitrous acid, a weak and unstable acid, is formed in situ from an aqueous solution of sodium nitrite and strong acids, such as hydrochloric acid or sulfuric acid, in cold conditions. In the presence of an acid, the nitrous acid gets protonated. The subsequent loss of water results in the formation of the electrophile known as nitrosonium ion.
Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Functional Groups02:45

Functional Groups

Functional groups are a group of atoms with characteristic properties, which when linked to the carbon skeleton of a molecule, alter the properties of that molecule. For example, the presence of certain functional groups on a molecule will make them hydrophilic, whereas others will make them hydrophobic. These functional groups are an indispensable part of organic chemistry and important components of biological molecules, such as carbohydrates, proteins, lipids, and nucleic acids. Each...
Classification and Mechanical Properties of Synthetic Polymers01:28

Classification and Mechanical Properties of Synthetic Polymers

Synthetic polymers are classified as elastomers, fibers, or plastics based on their crystallinity. Crystallinity, the degree of long-range order in the solid state, influences the mechanical properties (stretching or contracting) of elastomers. Elastomers are flexible polymers that can expand or contract easily upon the application of an external force. They have numerous crosslinks that pull them back into their original shape when stress is removed. Silicones, for instance, are highly elastic...

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相关实验视频

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Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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具有B2N2C2核的三烯类似物:合成,结构,氧化还原行为和光物理特性.

Cory A Jaska1, David J H Emslie, Michael J D Bosdet

  • 1Department of Chemistry, University of Calgary, 2500 University Drive North West, Calgary, Alberta, Canada T2N 1N4.

Journal of the American Chemical Society
|August 17, 2006
PubMed
概括

合成了具有B(2) N(2) C(2) 核的新型异芳香三烯类似物. 这些化合物具有不同的芳香度和结构性质,影响它们的电子行为和光.

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科学领域:

  • 有机化学 有机化学
  • 材料科学 材料科学 材料科学
  • 超分子化学 超分子化学

背景情况:

  • 三烯类似物因其独特的电子和结构性质而引起人们的兴趣.
  • 含和的异芳化合物为先进材料提供了可调节的特性.

研究的目的:

  • 为了合成新的B(2) N(2) C(2) 异芳香三烯类似物.
  • 研究这些新化合物的结构,电子和光物理性质.

主要方法:

  • 皮里达衍生物与迪博拉比烯基前体的化.
  • 核独立化学转移 (NICS) 计算用于芳香度评估.
  • 用于结构分析的X射线晶体学.
  • 电子偏磁共振 (EPR) 谱学用于基离子离子的表征.

主要成果:

  • 合成的基,基和基废除的B(2) N(2) C(2) 三烯类似物.
  • 根据NICS的计算,甲环具有较高的芳香度,而酸环具有较高的非芳香度.
  • 平面结构由未被替代的化面形成,而替代引发了扭曲的核心.
  • 由于分子间B...N相互作用,在平面物种中观察到的二元鱼骨包装.
  • 基离子被生成并进行了表征.
  • 平面类型的类型显示出弱光,而扭曲类型的类型是非光.

结论:

  • 核心B(2) N(2) C(2) 允许合成多种类型的三烯类似物.
  • 结构变化显著影响电子特性和光.
  • 分子间相互作用在固态包装和特性中发挥作用.