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Common Ion Effect03:24

Common Ion Effect

Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Châtelier’s principle. Consider the dissolution of silver iodide:
Metal-Ligand Bonds02:51

Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Ligand-gated Ion Channels01:19

Ligand-gated Ion Channels

Ligand-gated ion channels are transmembrane proteins with a channel for ions to pass through and a binding site for a ligand. The channel opens only when a ligand attaches to the binding site.
Three Subfamilies of Ligand-gated Ion Channels
Ligand-gated ion channels fall into three subfamilies. The 'Cys-loop' includes the nicotinic acetylcholine receptors, γ-aminobutyric acid (GABA), glycine, and 5-hydroxytryptamine receptors. The second one is the 'Pore-loop' channels that include the...
Indirect-Acting Cholinergic Agonists: Chemistry and Structure-Activity Relationship01:29

Indirect-Acting Cholinergic Agonists: Chemistry and Structure-Activity Relationship

Indirect-acting cholinergic agonists are agents that interact with the acetylcholinesterase enzyme in the synaptic cleft, preventing the breakdown of acetylcholine into choline and acetate. Consequently, the concentration of acetylcholine in the synaptic cleft increases. These agonists can be classified into reversible and irreversible inhibitors based on their duration of action.
Reversible inhibitors display short to medium durations of action. Short-acting agents include simple alcohols with...
Complexation Equilibria: The Chelate Effect01:19

Complexation Equilibria: The Chelate Effect

In complexation reactions, metal atoms or cations interact with ligands to form donor-acceptor adducts called metal complexes. Ligands that bind through one donor site are monodentate, ligands with two donor sites are bidentate, and those with more than two donor sites are polydentate ligands. For example, ethylene diamine is a bidentate ligand that binds through two nitrogen donor atoms, forming a five-membered ring. EDTA is a polydentate ligand that binds through four oxygen and two nitrogen...
Colloidal precipitates01:09

Colloidal precipitates

The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...

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Updated: Jun 7, 2026

Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides
11:04

Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides

Published on: September 7, 2019

离子作为激素聚合催化剂.

Timothy Clark1

  • 1Computer-Chemie-Centrum der Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen, Germany. clark@chemie.uni-erlangen.de

Journal of the American Chemical Society
|August 24, 2006
PubMed
概括
此摘要是机器生成的。

裸体离子通过促进基质添加而不是吸收来催化烯聚合. 这种由金属离子复合驱动的催化效应,使得非极性溶剂的有效链增长成为可能.

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Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides
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科学领域:

  • 物理化学 物理化学
  • 聚合物科学 聚合物科学
  • 计算化学计算化学

背景情况:

  • 由于竞争的原子抽象,olefins的激进聚合通常受到阻碍.
  • 金属离子可以影响有机合成中的反应途径.
  • 以前的实验工作表明,盐可以促进烯聚合.

研究的目的:

  • 为了研究"裸体"酸在烯酸根分子聚合中的催化作用.
  • 阐明离子对激素添加与抽象的影响机制.
  • 为了计算支持促进的基聚合物的实验观测.

主要方法:

  • 密度函数理论 (DFT) 的计算.
  • 开始的量子化学计算 (QCISD和CBS-RAD).
  • 反应路径和能量障碍的计算建模.

主要成果:

  • 离子复合有利于基基添加到烯基,而不是基的抽象.
  • 将三重氧气添加到烯酸中是热中性的,当复合到时,屏障较低.
  • 原子抽象也受到复合的青,但不如添加.

结论:

  • "裸体"离子通过选择性地促进链的传播,作为基聚合物的催化剂.
  • 氧气的介导复合促进了聚合的启动.
  • 计算结果与促进的基聚合物的实验证据一致.