硫同位素的证据表明有氧的阿基亚大气层
Hiroshi Ohmoto1, Yumiko Watanabe, Hiroaki Ikemi
1NASA Astrobiology Institute and Department of Geosciences, The Pennsylvania State University, University Park, Pennsylvania 16802, USA. ohmoto@geosc.psu.edu
Nature
|August 25, 2006
概括
在古老的澳大利亚岩石中没有质量独立的硫同位素 (MIF-S),这挑战了早期含氧大气的想法. 这一发现表明,MIF-S的起源可能不仅仅取决于大气化学.
科学领域:
- 地质化学 地质化学
- 同位素地质学的同位素.
- 古代大气层中的古气层.
背景情况:
- 在超过24亿年前的岩石中,硫同位素 (MIF-S) 的质量独立分离被认为表明无毒大气.
- 年轻岩石中MIF-S的缺失支持了向氧气大气的过渡,这归因于二氧化硫的紫外线光解.
研究的目的:
- 调查MIF-S在古代沉积岩中的存在和起源.
- 重新评估MIF-S与阿古时代大气氧水平之间的联系.
主要方法:
- 在2.76Gyr老的湖泊沉积物中,分析大约100米长的硫同位素.
- 在西澳大利亚皮尔巴拉克拉顿 (Pilbara Craton) 的2.92Gyr古海洋页岩中分析硫同位素.
主要成果:
- 在古老的湖泊沉积物和海洋页岩中检测到没有MIF-S.
- 这一发现与基于先前模型的预期MIF-S在这个年龄的岩石中的存在形成鲜明对比.
结论:
- MIF-S的地质记录可能需要重新解释.
- 可能的解释包括波动的Archaean氧气水平,火山活动影响MIF-S,或非光化学代谢过程创建MIF-S独立于大气化学.
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