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Compact Quantum Dots for Single-molecule Imaging
Published on: October 9, 2012
单分散的兰化氧硫化物纳米晶体
Fei Zhao1, Mei Yuan, Wen Zhang
1Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Journal of the American Chemical Society
|September 7, 2006
概括
使用热分解合成了兰化氧硫化物纳米结构. 这些纳米材料表现出独特的光特性,由于表面的修改,不同于散装.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 无机化学 无机化学
背景情况:
- 兰化氧硫化物是重要的.
- 控制纳米结构形态是调整光学属性的关键.
研究的目的:
- 合成单分散的兰化氧硫化物纳米板和纳米棒.
- 研究这些纳米结构的光特性.
- 了解表面修饰对光学行为的影响.
主要方法:
- 在含有氧气的大气中分子前体的热分解.
- 纳米结构形态和自我组织的表征.
- 合成纳米晶体的光发光谱学.
主要成果:
- 实现了单分散兰化氧硫化物纳米板和纳米棒的合成.
- 观察到纳米板的自我组织成微米级的纳米线.
- 合Eu2O2S和Eu3+的Gd2O2S纳米晶体显示出独特的光,与散装材料不同.
- 光变化归因于表面修饰效应.
结论:
- 成功合成可调节的兰化氧硫化物纳米结构.
- 证明了纳米尺度形态和表面效应对发光的显著影响.
- 为具有定制光学特性的新开发开辟了道路.
相关概念视频
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Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Schottky defects arise when some lattice points in a crystal, such as those in NaCl, remain unoccupied, creating lattice vacancies without disturbing the overall electrical neutrality of the crystal. This defect is common in ionic crystals where the positive and negative ions are similar in size, as seen in sodium chloride and cesium chloride. The presence of Schottky defects enables the crystal to conduct electricity to a small extent through an ionic mechanism. Electric fields cause nearby...

