一类非贵金属复合催化剂用于燃料电池
Rajesh Bashyam1, Piotr Zelenay
1Los Alamos National Laboratory, Materials Physics and Applications, Los Alamos, New Mexico 87545, USA.
Nature
|September 8, 2006
概括
研究人员开发了用于聚合物电解质燃料电池 (PEFC) 的低成本纳米复合材料催化剂. 这些非贵金属催化剂显示出高活性和耐用性,为负担得起的零排放汽车铺平了道路.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 能源转换 能源转换
背景情况:
- 聚合物电解质燃料电池 (PEFC) 是经济和零排放汽车的关键.
- 催化剂的高成本阻碍了PEFCs的商业可行性.
- 需要在PEFC电极中找到替代催化剂的经济有效的替代品.
研究的目的:
- 为 PEFC 阴极展示一类新的低成本纳米复合材料催化剂.
- 评估这些新型催化剂的减氧活性和耐用性.
- 探索异原子聚合物在稳定非贵金属和创建活性站点方面的作用.
主要方法:
- (非贵金属) / (异原子聚合物) 纳米复合材料催化剂的开发.
- 在H2-O2燃料电池中测试-多聚烯复合催化剂.
- 性能评估包括功率密度和耐用性测试超过100小时.
主要成果:
- 聚烯酸催化剂的功率密度大约为0.15W cm(-2).
- 催化剂在100多小时的运行时间内没有表现下降.
- 异原子聚合物在酸性PEFC阴极环境中有效地稳定了非贵金属.
结论:
- 非贵金属/异原子聚合物纳米复合材料为PEFC阴极提供了一个有希望的低成本替代品.
- 这些催化剂提供高氧减氧活性和良好的耐用性,解决的成本障碍.
- 异原子聚合物在催化剂稳定和活性位点生成中起着双重作用,以提高燃料电池性能.
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