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Facile Synthesis of Colloidal Lead Halide Perovskite Nanoplatelets via Ligand-Assisted Reprecipitation
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关于甲化纳米晶体形成的机制

Jonathan S Steckel1, Brian K H Yen, David C Oertel

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge 02139, USA.

Journal of the American Chemical Society
|October 5, 2006
PubMed
概括

两个机制解释了石化纳米晶体 (NC) 的形成. 有机素的纯度会影响NC产量,这表明了改善NC合成的方法.

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...