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在最不寻常的 furan Diels-Alder 反应中,结构和反应性的相互作用

Gerry A Griffith1, Ian H Hillier, Andrew C Moralee

  • 1Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, UK.

Journal of the American Chemical Society
|October 5, 2006
PubMed
概括

分化酸酸与酸发生快速循环添加反应,与它们的非化对应物不同. 密度函数理论 (DFT) 的计算揭示了由 (IV) 催化剂和溶剂稳定的极过渡状态,准确地预测了反应结果.

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