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Updated: Jul 18, 2026

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
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Published on: July 18, 2017

在Cu3中D2吸附的中子粉衍射研究 ((1,3,5-二甲酸) 2

Vanessa K Peterson1, Yun Liu, Craig M Brown

  • 1School of Chemistry, The University of Sydney, NSW 2006, Australia.

Journal of the American Chemical Society
|December 7, 2006
PubMed
概括

这项研究揭示了基于铜的金属有机框架 (Cu3(BTC) 2中的六个 (D2) 位点,主要位置在铜原子上,对于储存至关重要. 孔隙从最小填充到最大,随着载荷的增加.

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Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

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Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...