由于分别流动的液体引起的分子在表面上的协同拉动
1Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, USA.
Journal of the American Chemical Society
|December 15, 2006
概括
流动的极性液体可以沿碳纳米管表面驱动离子和极性分子. 这种由库伦比力驱动的分子运输与液体流速密切相匹配,这表明了潜在的应用.
科学领域:
- 纳米技术 纳米技术
- 物理化学 物理化学
- 流体动力学 流体动力学
背景情况:
- 了解纳米级分子运输对于开发先进材料和设备至关重要.
- 控制离子和极性分子的运动对于传感,分离和能量中的应用至关重要.
研究的目的:
- 通过流动的极性液体诱导的波动库伦比力来研究驱动离子和极性分子的现象.
- 模拟和分析由水流驱动的碳纳米管表面上小离子和极性分子的运输.
主要方法:
- 运用计算机模拟来建模在碳纳米管表面上流动的极性液体 (水) 和分子之间的相互作用.
- 分析的重点是和极分子在诱导库伦比力的影响下的动力学.
主要成果:
- 模拟表明,来自流动的极性液体的波动库伦比克力可以有效地驱动离子和极性分子.
- 发现驱动分子的平均速度与通过液体的速度相当.
- 这种现象是在分子和驱动液之间的纳米分离处观察到的.
结论:
- 这项研究证实,流动的极性液体可以在纳米尺度上诱导离子和极性分子的定向运动.
- 这些发现突出了分子运输的新机制,具有各种应用的巨大潜力.
相关概念视频
Van der Waals Interactions
Atoms and molecules interact with each other through intermolecular forces. These electrostatic forces arise from attractive or repulsive interactions between particles with permanent, partial, or temporary charges. The intermolecular forces between neutral atoms and molecules are ion–dipole, dipole–dipole, and dispersion forces, collectively known as van der Waals forces.Polar molecules have a partial positive charge on one end and a partial negative charge on the other end of the molecule,...
Intermolecular Forces in Solutions
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
Intermolecular Forces
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Intermolecular Forces
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Surface Tension, Capillary Action, and Viscosity
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
Coulomb's Law
Experiments with electric charges have shown that if two objects each have an electric charge, they exert an electric force on each other. The magnitude of the force is linearly proportional to the net charge on each object and inversely proportional to the square of the distance between them. The direction of the force vector is along the imaginary line joining the two objects and is dictated by the signs of the charges involved.
Newton's third law applies to the Coulomb force — the force on...
Newton's third law applies to the Coulomb force — the force on...


