半导体薄膜中微观结构的厚度依赖性 氧衍生物的半导体薄膜的厚度依赖性
Dean M DeLongchamp1, Mang Mang Ling, Youngsuk Jung
1Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA. deand@nist.gov
Journal of the American Chemical Society
|December 21, 2006
概括
我们开发了一种使用近端X射线吸收细结构 (NEXAFS) 谱学的新方法,用于测量有机半导体薄膜中的微结构. 这种技术揭示了分子方向和薄膜厚度如何影响电子性能,优化设备效率.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 频谱学是一种光谱学.
背景情况:
- 有机半导体薄膜中的微结构对电子性能产生了重大影响.
- 了解微结构的开发是优化有机电子设备的关键.
研究的目的:
- 展示一种测量微观结构厚度依赖在薄膜中的一般方法.
- 要将这种方法应用于氧化衍生物 (DDFTTF),并将微观结构与电子性质相关联.
主要方法:
- 使用了表面敏感的近边缘X射线吸收细结构 (NEXAFS) 光谱.
- 采用原子力显微镜 (AFM) 来确定露台高度.
- 使用分层技术来测量和孔的移动性.
主要成果:
- 在DDFTTF薄膜中独立确定芳香核和形末链的基质相对方向.
- 在DDFTTF膜 (6-150nm) 中确定了两个优选的微结构:在大型露台上垂直方向,在较小的领域中水平方向.
- 发现微结构分布取决于薄膜厚度,与基板的距离以及沉积过程中的基板温度.
- 相关的局部微观结构具有更大的pi轨道对齐,以改善局部和孔的流动性.
结论:
- 开发的NEXAFS方法为测量有机薄膜中的微结构厚度依赖提供了一种一般方法.
- DDFTTF膜表现出不同的微结构,受沉积条件的影响,影响电子性能.
- 通过可控沉积来优化微观结构可以增强有机半导体中的电荷传输.
相关概念视频
Fluid Mosaic Model
The fluid mosaic model was first proposed as a visual representation of research observations. The model comprises the composition and dynamics of membranes and serves as a foundation for future membrane-related studies. The model depicts the structure of the plasma membrane with a variety of components, which include phospholipids, proteins, and carbohydrates. These integral molecules are loosely bound, defining the cell’s border and providing fluidity for optimal function.LipidsThe most...
Membrane Fluidity
Cell membranes are composed of phospholipids, proteins, and carbohydrates loosely attached to one another through chemical interactions. Molecules are generally able to move about in the plane of the membrane, giving the membrane its flexible nature called fluidity. Two other features of the membrane contribute to membrane fluidity: the chemical structure of the phospholipids and the presence of cholesterol in the membrane.Fatty acids tails of phospholipids can be either saturated or...
Membrane Fluidity
Membrane fluidity is explained by the fluid mosaic model of the cell membrane, which describes the plasma membrane structure as a mosaic of components—including phospholipids, cholesterol, proteins, and carbohydrates—that gives the membrane a fluid character.
Mosaic nature of the membrane
The mosaic characteristic of the membrane helps the plasma membrane remain fluid. The integral proteins and lipids exist as separate but loosely-attached molecules in the membrane. The membrane is a relatively...
Mosaic nature of the membrane
The mosaic characteristic of the membrane helps the plasma membrane remain fluid. The integral proteins and lipids exist as separate but loosely-attached molecules in the membrane. The membrane is a relatively...
Mechanisms of Membrane-bending
The living membranes are flexible due to their fluid mosaic nature; however, their bending into different shapes is an active process regulated by specific lipids and proteins. The membrane bending can be transient as seen in vesicles or stable for a long time as in microvilli. Cells regulate the size, location, and duration of the membrane curvature.
Membrane bending can happen due to intrinsic changes in lipid composition or extrinsic association with different proteins. The proteins involved...
Membrane bending can happen due to intrinsic changes in lipid composition or extrinsic association with different proteins. The proteins involved...
Mechanisms of Membrane Domain Formation
Different physical properties of lipids and proteins allow them to localize and form distinct islands or domains in the membrane. Some membrane domains are formed due to protein-protein interactions, whereas others are formed due to the presence of specific lipids such as sphingolipids and sterols—for example, large proteins, such as bacteriorhodopsin, aggregate and create distinct domains.
Another mechanism for membrane domain formation involves membrane proteins interacting with cytoskeletal...
Another mechanism for membrane domain formation involves membrane proteins interacting with cytoskeletal...
Biosynthesis of Lipids
Microbial membranes exhibit remarkable diversity in lipid composition, reflecting evolutionary adaptations to various environmental conditions. The three domains of life—Bacteria, Archaea, and Eukarya—synthesize membrane lipids through distinct biosynthetic pathways, leading to fundamental structural differences that impact membrane stability, function, and adaptability.Fatty Acid-Based Lipids in Bacteria and EukaryaBacteria and eukaryotes share a common fatty acid biosynthesis pathway, which...


