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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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在 [16] 中的动态过程:annulene Möbius 键转移路径改变配置

Ryan P Pemberton1, Colleen M McShane, Claire Castro

  • 1Department of Chemistry, University of San Francisco, 2130 Fulton Street, San Francisco, CA 94117-1080, USA.

Journal of the American Chemical Society
|December 21, 2006
PubMed
概括

计算方法揭示了[16]annulene改变其配置的低能途径. 这些动态过程涉及Möbius拓过渡状态,解释了 annulenes 中容易发生的热配置变化.

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