在平流层火山爆发中的质量独立的硫同位素组成
Mélanie Baroni1, Mark H Thiemens, Robert J Delmas
1Laboratoire de Glaciologie et Géophysique de l'Environnement, CNRS/Université Joseph Fourier, 38400 St. Martin d'Hères, France. baroni@lgge.obs.ujf-grenoble.fr
概括
南极雪中的质量独立的硫同位素 (Delta33S) 揭示了火山的平流层事件. 这种可靠的追踪器随着时间的推移跟踪了快速的光化学二氧化硫氧化.
科学领域:
- 地质化学 地质化学
- 大气科学 大气科学
- 同位素地球化学 同位素地球化学
背景情况:
- 火山爆发将二氧化硫注入平流层,影响大气化学.
- 硫同位素,特别是质量独立分离 (Delta33S),为大气过程提供了洞察力.
研究的目的:
- 为了研究Delta33S在南极雪中的实用性,作为平流层火山事件的追踪器.
- 了解火山羽毛演化过程中Delta33S形成的时间尺度和机制.
主要方法:
- 在南极雪层中分析火山硫酸盐.
- 测量硫的同位素组成,特别是Delta33S.
主要成果:
- 在南极雪中观察到来自阿贡 (1963) 和皮纳图博 (1991) 喷发的Delta33S信号.
- 演示了Delta33S信号从正向负的时间转移.
- 通过二氧化硫到硫酸的光化学氧化,在一个月的时间尺度上指示快速的Delta33S形成.
结论:
- 南极雪中的Delta33S是记录平流层火山事件的可靠追踪器.
- 观察到的Delta33S变异证实了大气中的快速光化学过程.
- 可复制的Delta33S结果验证了其用于识别火山大气过程的使用.
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