按尺寸排序的阳离子氧化铁纳米磁铁作为磁热过热的环状介质
Jean-Paul Fortin1, Claire Wilhelm, Jacques Servais
1Laboratoire Matière et Systèmes Complexes, UMR CNRS 7057, University Paris 7, 140 rue de Lourmel, 75015 Paris, France.
Journal of the American Chemical Society
|February 3, 2007
概括
氧化铁纳米磁铁通过磁场暴露产生热量. 布朗的摩擦驱动着铁加热,而尼尔的放松主导着磁石加热,使可调节的高温应用成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 生物物理学的生物物理.
背景情况:
- 氧化铁合体纳米磁铁在交替磁场下产生热量.
- 加热效率取决于粒子大小,材料和溶剂特性.
- 了解磁能消散机制 (布罗恩和尼尔放松) 是至关重要的.
研究的目的:
- 区分尼尔和布朗机制对氧化铁纳米磁铁热量生成的贡献.
- 为了研究粒子大小,磁性异构和溶剂粘度对加热功率的影响.
- 为提供纳米磁铁加热效率的预测模型.
主要方法:
- 化学合成和电静止稳定阳离子磁石和铁酸盐纳米晶体.
- 使用连续的静电相分离对纳米粒子进行尺寸分类.
- 粒子大小,溶剂粘度,磁性异构和磁场参数的系统变化.
- 测量特定损失功率 (SLP) 并与预测模型进行比较.
主要成果:
- 一个预测模型准确地描述了特定的损失功率,考虑了尼尔和布朗的损失过程和粒子大小分布.
- 布朗摩擦是铁素颗粒的主要加热机制.
- 尼尔放松主导了磁石颗粒的加热力.
- 具体的损失功率因maghemite晶体大小而有三次数变化.
结论:
- 对于不同的氧化铁纳米晶体,已经确定了不同的加热机制 (布罗尼安和尼尔).
- 该研究提供了对影响纳米磁铁加热效率的因素的全面了解.
- 这些发现支持在各种应用中用于磁性诱导的高温症的阳离子合体纳米晶体的使用.
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