高Tc超导体的层工程: (Cu,Mo) Sr2 ((Ce,Y) 4Cu2O13+delta与CuO2平面之间的四重化物层块
Inga Grigoraviciute1, Hisao Yamauchi, Maarit Karppinen
1Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama 226-8503, Japan.
Journal of the American Chemical Society
|February 8, 2007
概括
研究人员合成了一种新的高Tc超导体,Tc为55K. 这一发现表明,在CuO2平面之间插入额外的化物层不会影响超导性,如果doping是恒定的.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 化学 化学 化学
背景情况:
- 铜氧化物中的高温超导性通常涉及化物结构层.
- 这些层在相邻的CuO2平面之间起到阻断块的作用.
研究的目的:
- 为了合成和描述一种新的高Tc超导相.
- 为了研究化石层厚度对超导性的影响.
主要方法:
- 在 (Cu,Mo) Sr2 ((Ce,Y) sCu2O ((5+2s+delta)) 同源系列中合成一个新阶段.
- 合成材料的特性,包括氧化和Tc测量.
主要成果:
- 一个新的阶段,一个12厚的四重化物层块成功合成了.
- 该材料具有55K的临界温度 (Tc) 的超导性.
- 在具有不同化物层厚度的同类系列的不同成员中,Tc保持不变,前提是孔 doping 水平保持不变.
结论:
- (Cu,Mo) -1242阶段代表了 (Cu,Mo) -Sr2 ((Ce,Y) sCu2O ((5+2s+delta)) 系列的新成员.
- 在这个系列中,超导特性,特别是Tc,对化层厚度的变化非常稳定.
- 孔剂水平是决定这些材料Tc的关键因素,而不是阻塞层的数量.
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