通过Mo K边缘扩展的X射线吸收细结构对NifEN上的Mo-Fe-S集群的识别
Simon J George1, Robert Y Igarashi, Cinthia Piamonteze
1Advanced Biological and Environmental X-ray Facility, Lawrence Berkeley National Laboratory, California 94720, USA.
Journal of the American Chemical Society
|February 24, 2007
概括
No abstract available in PubMed .
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When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
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According to Bragg's law, when X-rays strike the sample positioned on a stage, the rays are scattered by the electron clouds around the sample atoms. The X-ray diffraction or scattering is caused by constructive interference of the X-ray waves that reflect off the internal crystal...


