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一种基于二氧化的策略,用于 (-) - 特尔佩斯塔辛的总合成

Barry M Trost1, Guangbin Dong, Jennifer A Vance

  • 1Department of Chemistry, Stanford University, Stanford, CA 94305-5080, USA. bmtrost@stanford.edu

Journal of the American Chemical Society
|March 9, 2007
PubMed
概括

No abstract available in PubMed .

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Sharpless Epoxidation

The conversion of allylic alcohols into epoxides using the chiral catalyst was discovered by K. Barry Sharpless and is known as Sharpless epoxidation. The use of a chiral catalyst enables the formation of one enantiomer of the product in excess. This chiral catalyst is mainly a chiral complex of titanium tetraisopropoxide and tartrate ester (specific stereoisomer). The stereoisomer used in the chiral catalyst dictates the formation of the enantiomer of the product. In other words, the use of...