在有机场效应晶体管中的自我组装单层中注入电荷:奇偶偶效应
Pablo Stoliar1, Rajendra Kshirsagar, Massimiliano Massi
1Nanotechnology of Multifunctional Materials (NMM) Research Division, CNR-ISMN, Via Gobetti 101, I-40129 Bologna, Italy.
Journal of the American Chemical Society
|May 3, 2007
概括
自组装单层显著改变有机场效应晶体管的性能. 乙醇中的奇偶链长效应揭示了通过键道化,使晶体管成为单层电荷传输的敏感探头.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 表面化学 表面化学
背景情况:
- 有机场效应晶体管 (OFET) 对于灵活的电子产品至关重要.
- 接口工程是优化 OFET 性能的关键.
- 自组装单层 (SAM) 提供了对接口属性的精确控制.
研究的目的:
- 为了研究乙醇SAMs如何调节五烯OFET反应.
- 为了阐明电荷载体在有机金属接口上的注入机制.
- 探索使用OFET作为单层运输的敏感探头.
主要方法:
- 在源/排水电极上制造五烯OFET与乙醇SAM.
- 乙醇链长度 (n) 的系统变化.
- 测量和分析电荷载体移动性 (μ) 以及与链条长度的相关性.
主要成果:
- 电荷载体的移动性 (μ) 与乙醇链长度 (n) 有显著的奇偶波动.
- 对于短链 (n < 8),由于减少了注入障碍和改进了订单,移动性增加了.
- 对于长链 (n ≥ 8),移动性呈指数级下降 (β = 0.6 Å-1),表明通过键道.
- 观察到一个奇偶效应,与乙醇和乙烯之间的异性合有关.
结论:
- 电荷注入是通过接道穿过孔,由乙醇SAM介导.
- 在长链模式下,SAM介导的充电注入决定了OFET的性能.
- OFETs作为研究单个分子层中电荷传输的高度敏感平台.
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