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在交替的多聚合物共聚合物/富勒烯混合物中,双质电荷重组
Swati De1, Torbjörn Pascher, Manisankar Maiti
1Chemical Physics, Lund University, PO Box 124, SE-22100 Lund, Sweden.
Journal of the American Chemical Society
|June 15, 2007
概括
在聚合物/富勒烯太阳能电池中,快速双重组占据了低光强度下的电荷衰变,可能会阻碍在太阳光照明下有效收集电荷.
科学领域:
- 有机电子学有机电子学
- 太阳能材料科学 太阳能材料科学
背景情况:
- 聚合物/富勒烯混合物是有机太阳能电池的关键材料.
- 了解充电动态对于提高设备效率至关重要.
研究的目的:
- 为了研究聚烯共聚合物/富勒烯衍生物混合物的兴奋状态和电荷动态.
- 在太阳能电池相关条件下确定主导电荷衰变机制.
主要方法:
- 时间分辨率光谱法被用来监测过程在时间上的九个顺序.
- 测量是在两种光强度级别进行的.
主要成果:
- 观察到超快电荷光生成和较慢电荷重组.
- 双胞胎的重组 (大约. 30 ns) 是在低光强度下的主要衰变途径.
- 发现非主体重组的贡献是可以忽略不计的.
结论:
- 双胞胎重组显著影响这些系统中的电荷动态.
- 在运行条件下,这种快速的双重组合可能与聚合物/富勒烯太阳能电池中的电荷收集相竞争.
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