超原子化合物,集群和组件:超的图案和结构
Arthur C Reber1, Shiv N Khanna, A Welford Castleman
1Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284, USA.
Journal of the American Chemical Society
|July 28, 2007
概括
新的超原子化合物,结合超素 (团) 和超 (或氧化物),表现出独特的化学和电子特性. 这些新型材料为物理特征提供了前所未有的控制.
科学领域:
- 集群科学 集群科学 集群科学
- 材料化学 材料化学
- 计算化学的计算化学
背景情况:
- 特定大小和组成的集群可以作为超原子,模仿原子的行为.
- 集群 (Al(13)) 已经证明了与原子 (超素) 类似的特性.
研究的目的:
- 通过将超素 (Al(13)) 与超 (K(3) O,Na(3) O) 结合而形成的新型超原子化合物的研究.
- 探索这些新型超原子化合物的化学和可调节电子特征.
- 评估创造具有可控制性质的新材料的潜力.
主要方法:
- 采用了理论计算和计算建模.
- 分析电子结构和粘合特性.
- 对电离潜力和分子稳定性的研究.
主要成果:
- 由Al(13) 和K(3) O或Na(3) O组成的超原子化合物表现出新的化学和可调节的电子特征.
- (Al) (K) (O) 3具有非常低的电离潜力,作为一种超性基因.
- Al(13) K(3) O形成了一个强度结合的分子,使其能够组装成稳定的超原子组件 (Al(13) K(3) O) n.
结论:
- 将超素和超结合起来,可以产生具有独特性质的新型超原子化合物.
- 这些材料显示出创造具有可调整物理和电子特征的先进材料的潜力.
- 这些发现为设计基于超原子构件的材料开辟了新的途径.
相关概念视频
Classification of Elements and Compounds
Pure substances consist of only one type of matter. A pure substance can be an element or a compound. An element consists of only one type of atom, while a compound consists of two or more types of atoms held together by a chemical bond. Elements are classified as atomic or molecular based on the nature of their basic units.
Compounds are pure substances composed of two or more elements in fixed, definite proportions. Compounds are classified as ionic or molecular (covalent) based on the bonds...
Compounds are pure substances composed of two or more elements in fixed, definite proportions. Compounds are classified as ionic or molecular (covalent) based on the bonds...
Elements and Compounds
Pure substances consist of only one type of matter. A pure substance can be an element or a compound. An element consists of only one type of atom, while a compound consists of two or more types of atoms held together by a chemical bond.ElementsElements are classified as atomic or molecular based on the nature of their basic units. They are unique forms of matter with specific chemical and physical properties that cannot break down into smaller substances by ordinary chemical reactions. There...
Molecular Models
Physical models representing molecular architectures of chemical compounds play essential roles in understanding chemistry. The use of molecular models makes it easier to visualize the structures and shapes of atoms and molecules.
Ionic Crystal Structures
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Alkyl Halides
Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
Alkali Metals
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals


