液晶晶亚努斯类型的富勒罗登德里默体,表现出可调节的斑状柱状半形态
Julie Lenoble1, Stéphane Campidelli, Natacha Maringa
1Institut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, Case Postale 158, 2009 Neuchâtel, Switzerland.
Journal of the American Chemical Society
|July 31, 2007
概括
合成了斯类型的新型液晶富勒罗登德里默. 定制树突大小和类型可以控制状或柱状液晶相,C60不会影响中相类型.
科学领域:
- 超分子化学 超分子化学
- 材料科学 材料科学 材料科学
- 液晶是一种液晶.
背景情况:
- 体和体是先进的分子架构,具有独特的特性.
- 液晶呈现出固态和同otropic状态之间的有序相.
- 将这些结构结合在一起,为具有可调节性质的新型材料提供了潜力.
研究的目的:
- 为了合成雅努斯类型的液晶富勒罗登德里默.
- 为了研究树突结构和大小对液晶晶体行为的影响.
- 了解烯核在自我组装中的作用.
主要方法:
- 合成的1,3-双极循环添加反应.
- 极化光学显微镜,差分扫描热度计,和X射线衍射用于表征.
- 测量溶液属性 (双极矩,介电极化,克尔常数).
主要成果:
- 成功合成了雅努斯型的富勒罗登德里默.
- 基于树突基因的生成,实现了面状 (SmC,SmA) 或柱状 (Colr-c2mm,Colr-p2gg) 的半形态.
- 超分子组织受到树突大小,微分离,核心变形和双极相互作用的影响.
- C60核心不会改变形成的中位相的类型.
- 在溶液中观察到微分离.
结论:
- 富勒罗登德里默的液晶性质可以通过树突选择和大小通过设计精确控制.
- 富勒烯部分不决定中相类型,但对整体结构有所贡献.
- 这些发现提供了对复杂的超分子组件的结构属性关系的洞察.
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