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Updated: Jul 8, 2026

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对紫外线辅助 [4 + 2] 循环添加的机制研究在合成努力中对vibsanin E进行了辅助

Joachim Nikolai1, Øystein Loe, Paulina M Dominiak

  • 1Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, USA.

Journal of the American Chemical Society
|August 19, 2007
PubMed
概括

这项研究揭示了光化学循环添加中不寻常的立体选择性. 计算显示 cis-trans 异体化,其次是 Diels-Alder 反应,解释了观察到的产物分布.

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