概括
化水引入有毒化合物,如酸和氨酸进入沿海生态系统. 阳光可以将它们转化为持久的酸盐离子,其生态影响尚不清楚.
科学领域:
- 环境化学环境化学
- 海洋生物学 海洋生物学
- 生态毒理学 生态毒理学
背景情况:
- 越来越多的化水排放到河口和沿海环境中.
- 与水生系统中的天然化物和氨的反应性.
研究的目的:
- 为了识别和描述沿海水域消毒所产生的有毒副产品.
- 评估这些消毒副产品的环境命运和潜在风险.
主要方法:
- 河口和沿海水样本的化学分析.
- 研究与化物和氨的反应途径.
- 在模拟的阳光条件下监测消毒副产品的形成和持久性.
主要成果:
- 形成高度有毒的低酸,低酸离子和胺.
- 太阳光诱导的转化高达50%的酸盐离子.
- 酸盐离子被确定为天然水中的持久性化合物,毒性不明.
结论:
- 河口和沿海水域的化产生了大量有毒的副产品.
- 酸盐离子由于其持久性和未知的毒性而构成潜在的长期环境风险.
- 需要进一步的研究来了解酸盐离子对生态的影响.
相关概念视频
Acids, Bases and Neutralization Reactions
An acid-base reaction is one in which a hydrogen ion, H+, is transferred from one chemical species to another. Such reactions are of central importance to numerous natural and technological processes, ranging from the chemical transformations within cells or lakes and oceans to the industrial-scale production of fertilizers, pharmaceuticals, and other substances essential to the society.
Water: A Bronsted-Lowry Acid and Base
The reaction between a Brønsted-Lowry acid and water is called acid ionization. For example, when hydrogen fluoride dissolves in water and ionizes, protons are transferred from hydrogen fluoride molecules to water molecules, yielding hydronium ions and fluoride ions:
Ions as Acids and Bases
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
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Hydrolysis of acid halides is a nucleophilic acyl substitution reaction in which acid halides react with water to give carboxylic acids. The reaction occurs readily and does not require acid or a base catalyst.
As shown below, the mechanism involves a nucleophilic attack by water at the carbonyl carbon to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen π bond along with the departure of a halide ion. A final proton transfer step yields carboxylic acid...
As shown below, the mechanism involves a nucleophilic attack by water at the carbonyl carbon to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen π bond along with the departure of a halide ion. A final proton transfer step yields carboxylic acid...
Acids, Bases and Neutralization Reactions
Acids and bases play several important roles in biology. The pH of a biological system can significantly impact the function of biological molecules, including enzymes, proteins, and nucleic acids. For example, enzymes have optimal pH ranges for their activity, and changes in pH can denature or alter their structure, affecting their function. Acids and bases also play a crucial role in cellular signaling and communication. The pH of the extracellular fluid around cells can influence the...
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