相关实验视频
Updated: Jul 12, 2026

08:01
The Diffusion of Passive Tracers in Laminar Shear Flow
Published on: May 1, 2018
概括
液体流动性与分子扩张超出临界体积 (V(0) 直接相关,影响自我扩散和粘度. 这种关系适用于各种液体,挑战了一些关于液态的理论模型.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
背景情况:
- 液体的行为,特别是它们的流动性,对于理解各种化学和物理过程至关重要.
- 现有的理论模型有时过于简化了液体表现流动性的条件.
研究的目的:
- 为了建立液体流动性和分子膨胀之间的定量关系.
- 研究分子拥挤和排斥力在确定液体粘度和扩散性的作用.
主要方法:
- 开发了一个与粘度 (eta) 与摩拉体积 (V) 和临界体积 (V) 相关的比例方程.
- 分析了普通 (C3H8至C7H16) 和其他液体 (,四化碳,,二硫化碳,,) 的粘度数据.
主要成果:
- 粘度与摩拉体积的相对膨胀成反比例:1/eta = B[(V - V(0)) /V(0) ].
- 比率常数 (B) 对于较短的正常素是一致的,但随着链条长度的增加而下降.
- 对其他液体观察到B的变化,这表明与排斥力存在相关性.
- 证明液体可以是流体,即使扩张不到10%,这与一些理论相矛盾.
结论:
- 液体流动性基本上与分子扩张超出最小包装体积 (V(0) 的关系.
- 排斥力在各种液体类型的流动性中起着重要作用.
- 扩散性始于V = V ((0) 并且取决于温度,受溶液-溶剂相互作用的影响.
相关概念视频
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Viscosity
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The SI unit of viscosity is...
The SI unit of viscosity is...
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Distribution of Molecular Speeds
The motion of molecules in a gas is random in magnitude and direction for individual molecules, but a gas of many molecules has a predictable distribution of molecular speeds. This predictable distribution of molecular speeds is known as the Maxwell-Boltzmann distribution. The distribution of molecular speeds in liquids is comparable to that of gases but not identical and can help to understand the phenomenon of the boiling and vapor pressure of a liquid. Consider that a molecule requires a...
Behavior of Gas Molecules: Molecular Diffusion, Mean Free Path, and Effusion
Although gaseous molecules travel at tremendous speeds (hundreds of meters per second), they collide with other gaseous molecules and travel in many different directions before reaching the desired target. At room temperature, a gaseous molecule will experience billions of collisions per second. The mean free path is the average distance a molecule travels between collisions. The mean free path increases with decreasing pressure; in general, the mean free path for a gaseous molecule will be...

