概括
这项研究模拟了酸盐融中的聚合物单位,识别了像单体,二元体,链条,板块和3D单位这样的阳离子物种. 这些结构取决于非桥梁氧与 (NBO/Si) 的比率.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 频谱学是一种光谱学.
背景情况:
- 酸盐是复杂的混合物,具有多样化的聚合物结构.
- 了解这些结构对于地质学和材料科学至关重要.
- 之前的研究已经在酸盐系统中确定了各种阴离子单位.
研究的目的:
- 提出一个结构模型,用于酸盐融中的聚合物单位.
- 为了将已识别的离子物种与非桥接的氧与比 (NBO/Si) 相关联.
- 为了阐明不同融成分中的离子物种的平衡.
主要方法:
- 拉曼光谱法用于识别阴离子物种.
- 结构建模应用于灭的酸融化物.
- 进行了对非桥接氧基与四面体协调子 (NBO/Si) 的比率的分析.
主要成果:
- 已识别的离子单位包括SiO(4)(4-) 单体,Si(2)O(7)(6-) 双体,SiO(3)(2-) 链/环,Si(2)O(5)(2-) 板,以及SiO(2) 3D单位.
- 特定的NBO/Si范围与不同的共存的阳离子物种相关.
- 不成比例反应控制了酸,酸和多元组件化的阳离子物种.
结论:
- 基于NBO/Si比率的酸盐化的综合结构模型被介绍.
- 阳离子物种的平衡和共存是可以根据化的组成来预测的.
- 这个模型提供了对自然岩石融化的结构的洞察.
相关概念视频
Molecular and Ionic Solids
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Ionic Crystal Structures
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Ionic Association
The ionic association is the association of oppositely charged ions in an electrolyte solution to form ion pairs. Bjerrum defined ion pairs as two oppositely charged ions whose electrostatic attraction exceeds the thermal energy of the system, typically expressed as 2kT. Electrostatic attraction depends on ionic charge, separation distance, and the dielectric constant of the medium. Thermal energy, represented by kT, reflects the tendency of ions to move independently due to molecular motion.
Ionic Bonding and Electron Transfer
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
Ionic Strength: Overview
The ionic strength of a solution is a quantitative way of expressing the total electrolyte concentration of a solution. This concept was first introduced in 1921 by two American physical chemists, Gilbert N. Lewis and Merle Randall, while describing the activity coefficient of strong electrolytes. During the calculation of ionic strength (I or μ), all the cations and anions are considered. However, the concentration (c) of an ion with a greater charge number (z) has a greater contribution to...
Ionic Strength: Effects on Chemical Equilibria
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary cation—the calcium...
In this solution, the primary cation—the calcium...


