概括
液态和的粘度被估计到它们的临界温度. 发现和的临界绝对粘度高于范德瓦尔斯物质的临界绝对粘度.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 热力学是一种热力学.
背景情况:
- 了解液体金属在其临界点附近的行为对于各种工业应用至关重要.
- 以前的研究集中在上,但对和等金属的数据仍然有限.
研究的目的:
- 估计液体和的临界绝对粘度.
- 将这些金属的临界粘度与其他物质类型的临界粘度进行比较.
主要方法:
- 利用最近开发的一种粘度估计方法,此前用于.
- 对和的度数据进行抽取,以达到它们各自的临界温度.
主要成果:
- 的临界绝对粘度估计为0.072百度 (±0.01cp).
- 的临界绝对粘度估计为0.055百分比 (±0.01cp).
- 与范德瓦尔斯型共价或同极物质相比,金属具有更高的临界绝对粘度.
结论:
- 该研究提供了关于和的临界粘度的重要数据.
- 这些发现表明,金属和其他分子物质之间的临界粘度行为有明显的差异.
- 这项研究有助于更广泛地了解液体金属热力学和性能.
相关概念视频
Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility
Intermolecular forces are attractive forces that exist between molecules. They dictate several bulk properties, such as melting points, boiling points, and solubilities (miscibilities) of substances. Molar mass, molecular shape, and polarity affect the strength of different intermolecular forces, which influence the magnitude of physical properties across a family of molecules.
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
pV-Diagrams
The pV diagram, which is a graph of pressure versus volume of the gas under study, is helpful in describing certain aspects of the substance. When the substance behaves like an ideal gas, the ideal gas equation describes the relationship between its pressure and volume. On a pV diagram, it is common to plot an isotherm, which is a curve showing p as a function of V with the number of molecules and the temperature fixed. Then, for an ideal gas, the product of the pressure of the gas and its...
Liquid–Solid Solutions
The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...
Phase Transitions: Melting and Freezing
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
Freezing Point Depression and Boiling Point Elevation
When a non-volatile solute is added to a pure solvent, it results in the lowering of the freezing point of the solvent. This phenomenon is called freezing point depression. The extent to which the freezing point is lowered depends on the molality of the solute -the number of moles of solute per kilogram of solvent and the cryoscopic constant of the solvent.From the plot of chemical potential, μ, against temperature, it is evident that the μ of both solid and liquid solvents decrease with...
Freezing Point Depression and Boiling Point Elevation
Boiling Point Elevation
The boiling point of a liquid is the temperature at which its vapor pressure is equal to ambient atmospheric pressure. Since the vapor pressure of a solution is lowered due to the presence of nonvolatile solutes, it stands to reason that the solution’s boiling point will subsequently be increased. Vapor pressure increases with temperature, and so a solution will require a higher temperature than will pure solvent to achieve any given vapor pressure, including one...
The boiling point of a liquid is the temperature at which its vapor pressure is equal to ambient atmospheric pressure. Since the vapor pressure of a solution is lowered due to the presence of nonvolatile solutes, it stands to reason that the solution’s boiling point will subsequently be increased. Vapor pressure increases with temperature, and so a solution will require a higher temperature than will pure solvent to achieve any given vapor pressure, including one...


