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相关概念视频

Oxidative Cleavage of Alkenes: Ozonolysis01:46

Oxidative Cleavage of Alkenes: Ozonolysis

In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Carboxylic Acids to Methylesters: Alkylation using Diazomethane01:33

Carboxylic Acids to Methylesters: Alkylation using Diazomethane

Carboxylic acids react with diazomethane in an ether solvent via alkylation at the carboxylate oxygen atom to give methyl esters of the corresponding acid with excellent yields.
Hydroboration-Oxidation of Alkenes03:08

Hydroboration-Oxidation of Alkenes

In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
Oxymercuration-Reduction of Alkenes02:36

Oxymercuration-Reduction of Alkenes

Oxymercuration–reduction of alkenes is one of the major reactions converting alkenes to alcohols. It involves the hydration of alkenes with mercuric acetate in a mixture of tetrahydrofuran and water, forming an organomercury adduct. This is followed by a demercuration step in which the adduct is reduced to an alcohol using sodium borohydride.
Autoxidation of Ethers to Peroxides and Hydroperoxides02:23

Autoxidation of Ethers to Peroxides and Hydroperoxides

Ethers represent a class of chemical compounds that become more dangerous with prolonged storage because they tend to form explosive peroxides when standing in the air. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly oxidize to form hydroperoxides and dialkyl peroxides.
Ethers from Alkenes: Alcohol Addition and Alkoxymercuration-Demercuration02:35

Ethers from Alkenes: Alcohol Addition and Alkoxymercuration-Demercuration

Overview
Ethers can also be prepared from alkenes through acid-catalyzed addition of alcohols and alkoxymercuration–demercuration.
Preparation of Ethers by Acid-Catalyzed Addition of Alcohol to Alkenes
The acid-catalyzed addition of alcohol to an alkene involves treating the alkene with an excess of alcohol in the presence of an acid catalyst to form an ether under suitable conditions. The hydrogen will add to the less substituted carbon so that the nucleophile can attack the more substituted...

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相关实验视频

Updated: Jul 12, 2026

Original Experimental Approach for Assessing Transport Fuel Stability
09:48

Original Experimental Approach for Assessing Transport Fuel Stability

Published on: October 21, 2016

控制臭氧和使用甲醇燃料.

A G Russell, D St Pierre, J B Milford

    Science (New York, N.Y.)
    |January 12, 1990
    PubMed
    概括

    在车辆和燃烧中使用甲醇燃料可以显著减少臭氧污染. 洛杉矶的一项研究发现,甲醇燃料的使用降低了臭氧度和暴露,甲增加最小.

    科学领域:

    • 环境科学 环境科学
    • 大气化学 大气化学
    • 燃烧工程 燃烧工程

    背景情况:

    • 汽车排放和静止燃烧是城市空气污染的主要原因.
    • 臭氧 (O3) 是一种通过光化学反应形成的有害空气污染物.
    • 甲醇是一种潜在的替代燃料,其化学性能与汽油不同.

    研究的目的:

    • 为了模拟甲醇燃料使用对洛杉矶空气质量的影响.
    • 评估甲醇对臭氧和甲度的影响.
    • 为了比较纯甲醇 (M100) 与甲醇-汽油混合物 (M85) 的空气质量益处.

    主要方法:

    • 计算机建模模拟用于预测空气质量.
    • 该研究集中在加利福尼亚州洛杉矶,模拟了2000年和2010年的条件.
    • 评估了M100和M85燃料使用对臭氧和甲形成的影响.

    主要成果:

    • 模拟的M100燃料使用导致臭氧峰值水平降低高达16%.
    • 暴露于超出联邦标准的臭氧水平在M100.时降低了高达22%.
    • 甲水平和暴露并没有严重增加,有时与甲醇使用一起下降.

    更多相关视频

    Membraneless Hydrogen Peroxide Fuel Cells as a Promising Clean Energy Source
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    Combustion Chemistry of Fuels: Quantitative Speciation Data Obtained from an Atmospheric High-temperature Flow Reactor with Coupled Molecular-beam Mass Spectrometer
    07:24

    Combustion Chemistry of Fuels: Quantitative Speciation Data Obtained from an Atmospheric High-temperature Flow Reactor with Coupled Molecular-beam Mass Spectrometer

    Published on: February 19, 2018

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    Original Experimental Approach for Assessing Transport Fuel Stability
    09:48

    Original Experimental Approach for Assessing Transport Fuel Stability

    Published on: October 21, 2016

    Membraneless Hydrogen Peroxide Fuel Cells as a Promising Clean Energy Source
    06:39

    Membraneless Hydrogen Peroxide Fuel Cells as a Promising Clean Energy Source

    Published on: October 20, 2023

    Combustion Chemistry of Fuels: Quantitative Speciation Data Obtained from an Atmospheric High-temperature Flow Reactor with Coupled Molecular-beam Mass Spectrometer
    07:24

    Combustion Chemistry of Fuels: Quantitative Speciation Data Obtained from an Atmospheric High-temperature Flow Reactor with Coupled Molecular-beam Mass Spectrometer

    Published on: February 19, 2018

    结论:

    • 甲醇燃料,特别是M100,通过减少臭氧形成,显示出改善城市空气质量的巨大潜力.
    • 甲醇蒸汽的低化学反应性是其降低臭氧的关键.
    • 甲醇燃料的使用是减轻空气污染的可行策略,对甲水平有可管理的影响.