概括
这项研究揭示了水结构如何在微乳液中随着含水量增加而发生变化,从球体转变为圆柱体,再转变为片,影响光学和电气性能.
科学领域:
- 合体和表面科学科学
- 材料科学 材料科学 材料科学
背景情况:
- 微乳液是热力学稳定的,光学透明的油水分散.
- 了解它们的相位行为和结构过渡对于应用至关重要.
研究的目的:
- 为了研究六甲-六醇-油酸盐-水微乳液中的结构转变.
- 为了将这些转变与电阻和双断变化相关联.
主要方法:
- 制备具有不同水分含量的微乳液.
- 测量电阻和观察双断率.
- 高分辨率的核磁共振 (NMR) 光谱 (220 MHz).
主要成果:
- 随着水含量增加,观察到一个清-乱-清的过渡.
- 的区域表现出双折射和电阻的急剧下降.
- 核磁共振 (NMR) 数据显示,在双断裂区域有两个不同的水分子环境.
结论:
- 观察到的现象支持从水球到圆柱体到片的结构过渡.
- 水的分子环境在球形,圆柱形和状结构之间存在差异.
更多相关视频
09:38Fabrication Procedures and Birefringence Measurements for Designing Magnetically Responsive Lanthanide Ion Chelating Phospholipid Assemblies
Published on: January 3, 2018
14:55Atomic Scale Structural Studies of Macromolecular Assemblies by Solid-state Nuclear Magnetic Resonance Spectroscopy
Published on: September 17, 2017
相关概念视频
Cryo-electron Microscopy
Conventional electron microscopy (EM) involves dehydration, fixation, and staining of biological samples, which distorts the native state of biological molecules and results in several artifacts. Also, the high-energy electron beam damages the sample and makes it difficult to obtain high-resolution images. These issues can be addressed using cryo-EM, which uses frozen samples and gentler electron beams. The technique was developed by Jacques Dubochet, Joachim Frank, and Richard Henderson, for...
Bond Polarity, Dipole Moment, and Percent Ionic Character
Bond Polarity
Atomic Nuclei: Magnetic Resonance
The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external magnetic field, as the spins precess at the Larmor frequency, the excess population results in a net magnetization oriented along the z axis. When a pulse or a short burst of radio waves at the Larmor frequency is applied along the x axis, the coupling of frequencies causes resonance and flips the nuclear spins of the excess population from the...
Membrane Fluidity
Membrane fluidity is explained by the fluid mosaic model of the cell membrane, which describes the plasma membrane structure as a mosaic of components—including phospholipids, cholesterol, proteins, and carbohydrates—that gives the membrane a fluid character.
Mosaic nature of the membrane
The mosaic characteristic of the membrane helps the plasma membrane remain fluid. The integral proteins and lipids exist as separate but loosely-attached molecules in the membrane. The membrane is a relatively...
Mosaic nature of the membrane
The mosaic characteristic of the membrane helps the plasma membrane remain fluid. The integral proteins and lipids exist as separate but loosely-attached molecules in the membrane. The membrane is a relatively...
Molecular Geometry and Dipole Moments
The VSEPR theory can be used to determine the electron pair geometries and molecular structures as follows:
Overview of Electron Microscopy
The wavelengths of visible light ultimately limit the maximum theoretical resolution of images created by light microscopes. Most light microscopes can only magnify 1000X, and a few can magnify up to 1500X. Electrons, like electromagnetic radiation, can behave like waves, but with wavelengths of 0.005 nm, they produce significantly greater resolution up to 0.05 nm as compared to 500 nm for visible light. An electron microscope (EM) can create a sharp image that is magnified up to 2,000,000X.
