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相关概念视频

Determination of Crystal Structures01:29

Determination of Crystal Structures

In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...
Solubility of Ionic Compounds02:55

Solubility of Ionic Compounds

Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Precipitation of Ions03:11

Precipitation of Ions

Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
Electrolytes: van't Hoff Factor03:08

Electrolytes: van't Hoff Factor

Colligative Properties of ElectrolytesThe colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one dissolved...
Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary cation—the calcium...

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相关实验视频

Updated: Jul 11, 2026

Neutron Crystallography Data Collection and Processing for Modelling Hydrogen Atoms in Protein Structures
10:10

Neutron Crystallography Data Collection and Processing for Modelling Hydrogen Atoms in Protein Structures

Published on: December 1, 2020

从中子衍射直接确定离子溶解.

A H Narten, R L Hahn

    Science (New York, N.Y.)
    |September 24, 1982
    PubMed
    概括

    中子衍射直接探测三化物溶液中的离子-水相互作用. 结果揭示出一个独特的水合球体,每离子有8.6个氧原子和16.7个原子.

    科学领域:

    • 化学 化学 化学
    • 物理化学 物理化学
    • 材料科学 材料科学 材料科学

    背景情况:

    • 离子溶解对于理解电解质溶液至关重要.
    • 像光谱学和热力学这样的传统方法提供间接信息.
    • 直接探测离子-水相互作用一直是一个长期存在的挑战.

    研究的目的:

    • 直接研究溶液中离子的水合结构.
    • 使用中子衍射来明确确定离子-水协调.
    • 描述水分子在离子周围的空间布局.

    主要方法:

    • 在重水中的三化溶液上进行了中子衍射实验.
    • 离子的同位素替代被用于隔离特定的离子-水信号.
    • 对散射数据的分析为氧和原子提供了辐射分布函数.

    主要成果:

    • 在每个新离子周围确定了一个明确的第一个水化球体.
    • 每个离子都由8.6个氧原子以2.48安格斯特罗姆的速度协调.
    • 16.7个原子位于3.13安格斯特罗姆,这表明水分子与相距离离离子.

    结论:

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    Studying Soft-matter and Biological Systems over a Wide Length-scale from Nanometer and Micrometer Sizes at the Small-angle Neutron Diffractometer KWS-2

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    Published on: December 1, 2020

    High-Resolution Neutron Spectroscopy to Study Picosecond-Nanosecond Dynamics of Proteins and Hydration Water
    08:48

    High-Resolution Neutron Spectroscopy to Study Picosecond-Nanosecond Dynamics of Proteins and Hydration Water

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    Studying Soft-matter and Biological Systems over a Wide Length-scale from Nanometer and Micrometer Sizes at the Small-angle Neutron Diffractometer KWS-2
    11:27

    Studying Soft-matter and Biological Systems over a Wide Length-scale from Nanometer and Micrometer Sizes at the Small-angle Neutron Diffractometer KWS-2

    Published on: December 8, 2016

    • 中子衍射为研究离子溶解提供了一种直接而明确的方法.
    • 新离子表现出一种特定且有序的水化外结构.
    • 这些详细的结构信息增强了我们对电解质中的离子-水相互作用的理解.