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Updated: Jul 11, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

洞察通过密度函数理论对比阿酸氧化添加复合体的氨基结合和比阿酸胺复合体通过密度函数理论的减少消除

Timothy E Barder1, Stephen L Buchwald

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, USA. tbarder@mit.edu

Journal of the American Chemical Society
|September 14, 2007
PubMed
概括

化物复合体中大量的二甲基酸连接物复杂化了氨基结合,影响了催化氨基化路径. 新的机理性见解揭示了这些反应的比以前理解的更复杂的过程.

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Nucleophilic Aromatic Substitution: Elimination–Addition

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