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在涉及碳酸的酶机制中的合成效率:aristolochene synthase

Rudolf K Allemann1, Neil J Young, Shuhua Ma

  • 1School of Chemistry, Cardiff University, Park Place, Cardiff, CF10 3AT, U.K. allemannrk@cf.ac.uk

Journal of the American Chemical Society
|October 9, 2007
PubMed
概括

通过阿里斯托洛合成酶将法纳西酸 (FPP) 循环转化为 (+) -阿里斯托洛的新机制涉及直接的分子内质子转移,与以前的模型不同. 这种质子转移由酶促进,降低了激活能量,解释了基质的特异性.

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