Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Ionic Crystal Structures02:42

Ionic Crystal Structures

Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Intermolecular Forces03:13

Intermolecular Forces

Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
Aromatic Hydrocarbon Anions: Structural Overview01:18

Aromatic Hydrocarbon Anions: Structural Overview

Neutral hydrocarbons like cyclopentadiene with an odd number of carbon atoms and one intervening CH2 group in the ring are not aromatic. Cyclopentadiene with 4 π electrons does not satisfy the 4n + 2 π electron rule. Additionally, the intervening CH2 group is sp3 hybridized and lacks a vacant p orbital, thereby interrupting the overlap of p orbitals in a continuous manner and preventing the delocalization of π electrons throughout the ring.
Due to the absence of continuous overlap of p...
Ionic Association01:28

Ionic Association

The ionic association is the association of oppositely charged ions in an electrolyte solution to form ion pairs. Bjerrum defined ion pairs as two oppositely charged ions whose electrostatic attraction exceeds the thermal energy of the system, typically expressed as 2kT. Electrostatic attraction depends on ionic charge, separation distance, and the dielectric constant of the medium. Thermal energy, represented by kT, reflects the tendency of ions to move independently due to molecular motion.

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Coulombic Metal-Organic Frameworks Assembled from π-Stacked Organic Nodes and Polyoxometalate Inorganic Linkers.

Journal of the American Chemical Society·2026
Same author

Synthesis and crystal structure determination of aluminium hydroxide methane-sulfonate, Al(OH)(CH<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>.

Acta crystallographica. Section E, Crystallographic communications·2026
Same author

Synthesis of filled β-Mn-type ternary tellurides using a boron-tellurium reaction mixture.

Dalton transactions (Cambridge, England : 2003)·2026
Same author

Synthesis and Characterization of RE<sub>3</sub>LiSiSe<sub>7</sub> (RE = La-Nd, Sm, Gd, and Tb) Exhibiting Enhanced Nonlinear Optical (NLO) Properties.

Inorganic chemistry·2026
Same author

Increasing connectivity through self-complementarity enables permanent porosity in a halogen-bonded organic framework.

Chemical science·2026
Same author

Synthesis of Unusually High Valent Perovskite Oxide from the Highly Oxidized Coprecipitation Precursor.

Journal of the American Chemical Society·2026

相关实验视频

Updated: Jul 10, 2026

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid
08:54

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid

Published on: January 25, 2020

固态中的阴离子相互作用和极性结构.

Michael R Marvel1, Julien Lesage, Jaewook Baek

  • 1Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113, USA.

Journal of the American Chemical Society
|October 20, 2007
PubMed
概括

阳离子在KNaNbOF5.5.2中的氧化 ([NbOF5]2-) 离子的非中心包装中发挥着至关重要的作用. 这与CsNaNbOF5形成鲜明对比,揭示了对晶体结构和物理性质的洞察力.

科学领域:

  • 无机化学 无机化学
  • 固态化学 固态化学
  • 晶体学 晶体学是指结晶学.

背景情况:

  • 有氧和的复杂结构经常表现出独特的物理性质.
  • 在这种框架中,偏离保林的第二个晶体规则 (PSCR) 是常见的.
  • [NbOF5]2-离子的结构和结合是理解材料特性的关键.

研究的目的:

  • 研究KNaNbOF5和CsNaNbOF5.5中的[NbOF5]2-离子的结构排序.
  • 分析金属酸 (Na+,K+,Cs+) 在这些酸盐的包装和对称性中的作用.
  • 探索与晶体结构相关的PSCR和债券价值模型的偏差.

主要方法:

  • 单晶X射线衍射以确定晶体结构和晶格参数.
  • 对键长度 (Nb-O,Nb-F) 和协调环境的分析.
  • 债券价值模型的应用,以评估阴离子-离子相互作用.

主要成果:

  • KNaNbOF5在极空间组Pna21中结晶,在[NbOF5]2-阳离子中具有有序的Nb-O和Nb-F键.
  • CsNaNbOF5 在中心对称空间组Pbcn.中结晶.
  • 这项研究强调了小离子对[NbOF5]2-离子的非中心对称排列的显著影响.

更多相关视频

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
06:35

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

Published on: February 15, 2016

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

相关实验视频

Last Updated: Jul 10, 2026

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid
08:54

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid

Published on: January 25, 2020

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
06:35

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

Published on: February 15, 2016

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

结论:

  • 金属离子体的存在和大小极大地影响[NbOF5]2-基化合物的晶体对称性和包装.
  • 观察到与PSCR的偏差,并通过特定的阴离子-离子相互作用来解释.
  • 了解这些结构细微差别对于预测和调整相关无机材料的物理性质至关重要.