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Updated: Jul 10, 2026

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene
08:44

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene

Published on: August 22, 2017

C60-PMO:周期性半孔布基球

Wesley Whitnall1, Ludovico Cademartiri, Geoffrey A Ozin

  • 1Center for Inorganic and Polymeric Nanomaterials, Materials Chemistry and Nanochemistry Research Group, Chemistry Department, University of Toronto, Toronto, Ontario, Canada M5S 3H6.

Journal of the American Chemical Society
|November 21, 2007
PubMed
概括

研究人员合成了一种新型的周期性半孔有机 (PMO) 材料C60-PMO,将buckminsterfullerene (C60) 整合到其框架中. 这种新材料具有高C60含量和均分布,为先进的应用开辟了道路.

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π Molecular Orbitals of 1,3-Butadiene01:24

π Molecular Orbitals of 1,3-Butadiene

Conjugated dienes have lower heats of hydrogenation than cumulated and isolated dienes, making them more stable. The enhanced stabilization of conjugated systems can be understood from their π molecular orbitals.
The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the number...